### Sources of Martian Methane
Methane () gas detected in the atmosphere of Mars has sparked debate regarding its origin. Because is rapidly destroyed by solar radiation and chemical reactions in the Martian atmosphere, any detected methane must have been recently released. Two models have been proposed to explain the origin of this methane.
* Model 1 (Biogenic Source): Methane is produced by subsurface methanogenic microorganisms. These microbes use carbon dioxide () and hydrogen () to produce energy, releasing as a metabolic waste product. The microbes inhabit deep liquid water reservoirs where temperatures are warm enough for cellular activity. As crustal temperatures rise during the Martian summer, pressure gradients push the accumulated gas through seasonal fissures in the soil and into the atmosphere.
* Model 2 (Abiogenic Source): Methane is produced through serpentinization, an inorganic geochemical reaction between water (), dissolved carbon dioxide (), and olivine minerals in the Martian crust. This reaction occurs at high temperatures (typically above ) in deep, geologically active zones. The produced is trapped inside sub-surface water-ice cages called clathrate hydrates. During seasonal warming, the thermal decomposition of these hydrates releases gas, which migrates to the surface.
Planetary scientists have collected new experimental observations and data from Martian orbiters and rovers. Match each of the new findings on the left to the statement on the right that best describes how that finding supports or contradicts the proposed models.
- Finding A: Carbon isotope analysis of atmospheric methane shows an enrichment of carbon-12 () relative to carbon-13 (), a signature associated with biological enzymes.Supports Model 1, because biological organisms preferentially select lighter carbon isotopes () during carbon fixation.
- Finding B: High-resolution thermal mapping of the Martian crust shows that subsurface temperatures do not exceed in any geologically active zones.Contradicts Model 2, because serpentinization reactions require temperatures above to generate significant amounts of methane.
- Finding C: Atmospheric scans identify that methane plumes are consistently accompanied by ethane (), a gaseous hydrocarbon produced alongside methane in geochemical reactions.Supports Model 2 over Model 1, because geochemical pathways produce co-released ethane, whereas methanogenic microbes do not produce ethane.
- Finding D: Atmospheric monitoring shows that methane levels rise and fall in direct correlation with seasonal surface temperature fluctuations.Is consistent with both Model 1 and Model 2, because both models describe temperature-dependent mechanisms for releasing methane into the atmosphere.