Question

Difficulty: HardDirect and Inverse Proportionality

A student conducted a series of trials to investigate Fick's first law of diffusion using a synthetic membrane. The rate of diffusion of a solute, JJ (in milligrams per second, mg/s\text{mg/s}), is directly proportional to both the surface area of the membrane, AA (in square centimeters, cm2\text{cm}^2), and the concentration difference of the solute across the membrane, ΔC\Delta C (in moles per liter, mol/L\text{mol/L}), and is inversely proportional to the thickness of the membrane, xx (in millimeters, mm\text{mm}).

The parameters for Trial 1 and Trial 2 are shown in the table below:

TrialMembrane thickness, xx (mm\text{mm})Membrane surface area, AA (cm2\text{cm}^2)Concentration difference, ΔC\Delta C (mol/L\text{mol/L})Diffusion rate, JJ (mg/s\text{mg/s})
10.200.203.03.00.060.0627.027.0
20.600.608.08.00.040.04?

Based on the table, what was the resulting diffusion rate of the solute in Trial 2, in mg/s\text{mg/s}?

Answer: 16 mg/s

Answer

The diffusion rate of the solute in Trial 2 is 16.0 mg/s.
By setting up the proportionality equation J=kAΔCxJ = k \frac{A \cdot \Delta C}{x}, we find the constant k=30k = 30 using the parameters from Trial 1. Substituting the parameters from Trial 2 yields a diffusion rate of exactly 16.0 mg/s.

Step-by-Step Solution

1
Set up the algebraic relationship for the variables based on proportionality rules.
J=kAΔCxJ = k \frac{A \cdot \Delta C}{x}
The rate of diffusion (JJ) is directly proportional to the surface area (AA) and concentration difference (ΔC\Delta C), meaning they appear in the numerator. It is inversely proportional to membrane thickness (xx), meaning it appears in the denominator. Here, kk represents the constant of proportionality.
2
Calculate the constant of proportionality, kk, using the values provided for Trial 1.
k=30k = 30
Substitute J1=27.0J_1 = 27.0, A1=3.0A_1 = 3.0, ΔC1=0.06\Delta C_1 = 0.06, and x1=0.20x_1 = 0.20 into the equation: 27.0=k3.0×0.060.20    27.0=0.9k    k=3027.0 = k \frac{3.0 \times 0.06}{0.20} \implies 27.0 = 0.9k \implies k = 30.
3
Calculate the diffusion rate for Trial 2, J2J_2, by substituting the new parameters and the calculated constant kk into the equation.
J2=16.0J_2 = 16.0
Substitute k=30k = 30, A2=8.0A_2 = 8.0, ΔC2=0.04\Delta C_2 = 0.04, and x2=0.60x_2 = 0.60 into the equation: J2=30×8.0×0.040.60=30×0.320.60=16.0J_2 = 30 \times \frac{8.0 \times 0.04}{0.60} = 30 \times \frac{0.32}{0.60} = 16.0.

Key Concept

Direct and Inverse Proportionality
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