Question

Difficulty: HardChemical Reactions and Compounds

In an industrial metal recovery process, solid aluminum reacts with an aqueous solution of copper(II) sulfate according to the unbalanced chemical equation:

Al(s)+CuSO4(aq)→Al2(SO4)3(aq)+Cu(s)\text{Al}(s) + \text{CuSO}_4(aq) \rightarrow \text{Al}_2(\text{SO}_4)_3(aq) + \text{Cu}(s)

When this equation is completely balanced using the smallest possible whole-number coefficients, what is the sum of all the stoichiometric coefficients?

  1. A
    44
  2. B
    88
  3. 99Answer
  4. D
    77

Answer

The sum of all stoichiometric coefficients in the balanced equation is 99.
Balancing the equation requires 22 aluminum atoms and 33 copper(II) sulfate units to react to form 11 unit of aluminum sulfate and 33 copper atoms: 2Al(s)+3CuSO4(aq)→1Al2(SO4)3(aq)+3Cu(s)2\text{Al}(s) + 3\text{CuSO}_4(aq) \rightarrow 1\text{Al}_2(\text{SO}_4)_3(aq) + 3\text{Cu}(s). Summing all four stoichiometric coefficients gives 2+3+1+3=92 + 3 + 1 + 3 = 9.

Step-by-Step Solution

1
Count the number of each type of atom/polyatomic ion in the unbalanced equation.
Reactants: 1 Al1\text{ Al}, 1 Cu1\text{ Cu}, 1 SO42−1\text{ SO}_4^{2-}. Products: 2 Al2\text{ Al}, 1 Cu1\text{ Cu}, 3 SO42−3\text{ SO}_4^{2-}.
Establishing initial quantities identifies which species violate the Law of Conservation of Mass.
2
Balance the polyatomic sulfate groups by placing a coefficient of 33 before CuSO4\text{CuSO}_4.
Al+3CuSO4→Al2(SO4)3+Cu\text{Al} + 3\text{CuSO}_4 \rightarrow \text{Al}_2(\text{SO}_4)_3 + \text{Cu}
Treating polyatomic ions as single units when they remain intact simplifies balancing.
3
Balance the aluminum and copper atoms by adding coefficients of 22 to Al\text{Al} and 33 to Cu\text{Cu}.
2Al+3CuSO4→1Al2(SO4)3+3Cu2\text{Al} + 3\text{CuSO}_4 \rightarrow 1\text{Al}_2(\text{SO}_4)_3 + 3\text{Cu}
Ensures equal numbers of each elemental atom on both the reactant and product sides.
4
Sum all lowest whole-number coefficients, including the implicit coefficient of 11.
2+3+1+3=92 + 3 + 1 + 3 = 9
Calculates the total coefficient sum requested in the problem.

Key Concept

Balancing chemical equations according to the Law of Conservation of Mass using lowest whole-number stoichiometric coefficients.
Estimated Time:1m 15s
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