Question

Difficulty: MediumConductors, Insulators, and Semiconductors

During the inspection of industrial control cabling, an electrical technician notes that the cable consists of an annealed copper core surrounded by a polyvinyl chloride (PVC) jacket. What fundamental atomic property explains why the copper core acts as a conductor while the PVC jacket acts as an insulator?

  1. A
    Copper atoms have four valence electrons that form a rigid covalent matrix, while PVC molecules have a single loosely held electron per atom.
  2. Copper atoms possess loosely bound valence electrons that drift freely under an electric field, while PVC molecules hold their valence electrons tightly in stable chemical bonds.Answer
  3. C
    Copper atoms conduct electricity through the migration of positive atomic nuclei, while PVC blocks only negatively charged particles.
  4. D
    Copper atoms maintain completely filled outer valence shells of eight electrons, while PVC molecules contain unfilled shells with high free electron mobility.

Answer

Copper contains loosely bound valence electrons that drift freely when voltage is applied, whereas PVC holds its valence electrons tightly within stable chemical bonds, preventing electron flow.
Good electrical conductors such as copper have outermost valence electrons that are loosely held by the nucleus, allowing them to detach easily and drift as an electric current under an applied electromotive force. In contrast, insulating materials such as PVC hold their valence electrons tightly in stable chemical bonds, leaving virtually no free charge carriers available to conduct electricity.

Step-by-Step Solution

1
Examine the atomic structure of metallic conductors such as copper.
Copper has a single valence electron in its outermost shell (4s14s^1) that is weakly attracted to the nucleus.
This weak atomic bond allows the electron to easily detach and become a mobile free electron when an electromotive force is applied.
2
Examine the atomic bonding structure of insulators such as PVC.
PVC is composed of long polymer chains where valence electrons are tightly shared and locked in stable covalent bonds.
Because no free electrons are available to move between atoms, the material exhibits extremely high electrical resistance.
3
Compare the mobility of valence electrons in both materials.
The availability of free, mobile valence electrons in copper enables electrical conduction, while the absence of mobile electrons in PVC provides electrical insulation.
The degree of valence electron mobility is the primary physical characteristic that separates conductors from insulators.

Key Concept

Valence electron mobility in conductors versus insulators
Estimated Time:45s
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