Question

Difficulty: HardMixture and Concentration

A laboratory container initially holds 120120 liters of a chemical solution that is 40%40\% acid by volume. A chemist removes xx liters of the solution and replaces it with an equal volume of pure acid. Next, the chemist removes xx liters of the resulting mixture and replaces it with an equal volume of pure water. If the final concentration of acid in the container is 40%40\% by volume, what is the value of xx?

  1. A
    2020
  2. B
    3030
  3. 4040Answer
  4. D
    5050
  5. E
    6060

Answer

The value of xx is 4040.
The initial amount of acid is 120×0.40=48120 \times 0.40 = 48 liters. After replacing xx liters with pure acid, the amount of acid becomes 480.40x+x=48+0.60x48 - 0.40x + x = 48 + 0.60x liters. Removing xx liters of this intermediate solution removes a fraction x120\frac{x}{120} of its acid, leaving (48+0.60x)(1x120)(48 + 0.60x)\left(1 - \frac{x}{120}\right) liters. Adding pure water does not add acid. Setting this equal to the final acid quantity of 4848 liters yields the equation (48+0.60x)(120x)=5760(48 + 0.60x)(120 - x) = 5760, which simplifies to 24x0.60x2=024x - 0.60x^2 = 0. Solving for non-zero xx gives x=40x = 40.

Step-by-Step Solution

1
Calculate initial acid quantity and acid quantity after the first replacement.
Initial acid = 120×0.40=48120 \times 0.40 = 48 liters. Removing xx liters of 40%40\% solution removes 0.40x0.40x liters of acid. Adding xx liters of pure acid gives a new acid quantity of 480.40x+x=48+0.60x48 - 0.40x + x = 48 + 0.60x liters.
Pure acid contains 100%100\% acid, so replacing xx liters adds 1.00x1.00x acid while removing 0.40x0.40x acid.
2
Determine the acid quantity after the second replacement.
The solution concentration after Step 1 is 48+0.60x120\frac{48 + 0.60x}{120}. Removing xx liters removes a fraction x120\frac{x}{120} of the solution, leaving a fraction (1x120)\left(1 - \frac{x}{120}\right). Replacing with pure water adds 00 acid, so final acid quantity is (48+0.60x)(1x120)(48 + 0.60x)\left(1 - \frac{x}{120}\right).
Pure water contributes 0%0\% acid to the total solute count.
3
Set up and solve the equation for the final acid amount.
(48+0.60x)(120x120)=48    (48+0.60x)(120x)=5760(48 + 0.60x)\left(\frac{120 - x}{120}\right) = 48 \implies (48 + 0.60x)(120 - x) = 5760. Expanding gives 576048x+72x0.60x2=5760    24x0.60x2=05760 - 48x + 72x - 0.60x^2 = 5760 \implies 24x - 0.60x^2 = 0. Since x>0x > 0, 0.60x=24    x=400.60x = 24 \implies x = 40.
The final concentration is given as 40%40\%, which corresponds to 4848 liters of acid in 120120 liters total volume.

Key Concept

Multi-stage mixture dilution and replacement equations using solute mass balance.
Estimated Time:2m 0s
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