Question

Difficulty: MediumGeneral Gas Law, Ideal Gas Equation, and Molar Volume

A gas sample collected in a laboratory syringe occupies a volume of 600 cm3600\text{ cm}^3 at 27C27^\circ\text{C} and 1.0 atm1.0\text{ atm} pressure. What is the volume of the gas when the pressure is increased to 2.0 atm2.0\text{ atm} and the temperature is raised to 81C81^\circ\text{C}?

  1. 354 cm3354\text{ cm}^3Answer
  2. B
    900 cm3900\text{ cm}^3
  3. C
    708 cm3708\text{ cm}^3
  4. D
    1416 cm31416\text{ cm}^3

Answer

The final volume of the gas is 354 cm3354\text{ cm}^3.
Using the General Gas Law P1V1T1=P2V2T2\frac{P_1 V_1}{T_1} = \frac{P_2 V_2}{T_2} with absolute temperatures T1=300 KT_1 = 300\text{ K} (27C27^\circ\text{C}) and T2=354 KT_2 = 354\text{ K} (81C81^\circ\text{C}), the calculation yields V2=1.0×600×3542.0×300=354 cm3V_2 = \frac{1.0 \times 600 \times 354}{2.0 \times 300} = 354\text{ cm}^3.

Step-by-Step Solution

1
Convert temperatures from Celsius to Kelvin
T1=27+273=300 KT_1 = 27 + 273 = 300\text{ K} and T2=81+273=354 KT_2 = 81 + 273 = 354\text{ K}
Gas laws require absolute temperature values on the Kelvin scale.
2
Set up the General Gas Law equation
P1V1T1=P2V2T2    V2=P1V1T2P2T1\frac{P_1 V_1}{T_1} = \frac{P_2 V_2}{T_2} \implies V_2 = \frac{P_1 V_1 T_2}{P_2 T_1}
Pressure, volume, and temperature all change simultaneously for a fixed mass of gas.
3
Substitute the known values and calculate V2V_2
V2=1.0 atm×600 cm3×354 K2.0 atm×300 K=354 cm3V_2 = \frac{1.0\text{ atm} \times 600\text{ cm}^3 \times 354\text{ K}}{2.0\text{ atm} \times 300\text{ K}} = 354\text{ cm}^3
Simplifying 6002.0×300=1\frac{600}{2.0 \times 300} = 1 leaves 1×354=354 cm31 \times 354 = 354\text{ cm}^3.

Key Concept

General Gas Law (Combined Gas Law)
Estimated Time:1m 15s
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