Question

Difficulty: EasyWeathering and Mass Wasting Processes

Carbonation is a primary chemical weathering process that degrades limestone landscapes. What is the correct chronological sequence of steps involved in carbonation, from the initial formation of acidic rainwater to the final removal of dissolved rock materials?

  1. 1Carbon dioxide dissolves in falling atmospheric rainwater to form weak carbonic acid.
  2. 2Acidic rainwater percolates through rock joints and bedding planes of exposed limestone.
  3. 3Carbonic acid chemically reacts with insoluble calcium carbonate to transform it into soluble calcium bicarbonate.
  4. 4Soluble calcium bicarbonate is carried away in solution by groundwater, widening joints and forming karst landforms.

Answer

The correct sequence begins with carbon dioxide dissolving in rainwater to form carbonic acid, followed by acidic rainwater contacting limestone, chemical reaction forming soluble calcium bicarbonate, and finally the removal of dissolved calcium bicarbonate in solution by water.
Carbonation begins when carbon dioxide dissolves in rainwater to form weak carbonic acid. When this acidic rainwater contacts limestone, it converts insoluble calcium carbonate into soluble calcium bicarbonate, which is subsequently washed away in solution by moving water.

Step-by-Step Solution

1
Identify the initial chemical reaction in the atmosphere.
Rainwater absorbs carbon dioxide to form weak carbonic acid (CO2+H2OH2CO3CO_2 + H_2O \rightarrow H_2CO_3).
Chemical weathering cannot begin until the chemical weathering agent is synthesized in precipitation.
2
Trace the movement of the acid solution onto rock surfaces.
Acidic rainwater flows along limestone joints and bedding planes.
The acid must infiltrate the rock structure to react with calcium carbonate minerals.
3
Determine the chemical conversion of the rock mineral.
Carbonic acid reacts with calcium carbonate to form soluble calcium bicarbonate (CaCO3+H2CO3Ca(HCO3)2CaCO_3 + H_2CO_3 \rightarrow Ca(HCO_3)_2).
Insoluble rock material is converted into a dissolved compound.
4
Identify the final removal of dissolved material.
Groundwater washes away dissolved calcium bicarbonate in solution.
Continuous removal of soluble minerals enlarges joints, producing caves and karst features.

Key Concept

Chemical weathering of limestone via carbonation
Estimated Time:1m 0s
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