Question

Difficulty: MediumGreenhouse Effect, Global Warming, and Ozone Layer Depletion

Which of the following atmospheric pollutants acts primarily as a greenhouse gas by absorbing terrestrial infrared radiation, rather than destroying stratospheric ozone through catalytic radical chain reactions?

  1. Carbon(IV) oxide (CO2CO_2)Answer
  2. B
    Dichlorodifluoromethane (CF2Cl2CF_2Cl_2)
  3. C
    Nitrogen(II) oxide (NONO)
  4. D
    Trichlorofluoromethane (CCl3FCCl_3F)

Answer

Carbon(IV) oxide (CO2CO_2)
Carbon(IV) oxide (CO2CO_2) functions primarily as a greenhouse gas by absorbing outgoing terrestrial infrared radiation and re-radiating it back toward the Earth's surface. Unlike chlorofluorocarbons or nitric oxide, CO2CO_2 does not photolytically generate free radicals that decompose stratospheric ozone.

Step-by-Step Solution

1
Analyze the environmental mechanism described in the stem.
The mechanism specifies absorbing re-radiated longwave infrared radiation from the Earth's surface (greenhouse effect) in the troposphere, rather than catalytic free radical destruction of ozone (O3O_3) in the stratosphere.
Greenhouse gases retain heat energy in the lower atmosphere, whereas ozone-depleting substances release reactive species that decompose stratospheric ozone.
2
Evaluate the chemical behavior of each listed atmospheric gas.
Carbon(IV) oxide (CO2CO_2) is a major greenhouse gas responsible for trapping infrared heat. Chlorofluorocarbons (CF2Cl2CF_2Cl_2 and CCl3FCCl_3F) and nitrogen(II) oxide (NONO) act as catalysts in stratospheric ozone depletion.
Halogen radicals (ClCl^\bullet) cleaved from CFCs by UV light and nitric oxide radicals (NONO) catalyze ozone decomposition, whereas CO2CO_2 does not react with stratospheric ozone.

Key Concept

Distinguishing greenhouse gases (infrared radiation absorbers) from ozone-depleting substances (free radical catalysts).
Estimated Time:1m 0s
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