Question

Difficulty: HardLatent Heat and Changes of State

A vessel of negligible heat capacity contains 0.20 kg0.20\text{ kg} of a liquid at its boiling point of 100C100^\circ\text{C}. An electric heating element rated at 500 W500\text{ W} is immersed in the liquid and switched on for 3.0 minutes3.0\text{ minutes}. If 0.040 kg0.040\text{ kg} of the liquid is vaporized during this period, what is the specific latent heat of vaporization of the liquid?

  1. 2.25×106 J kg12.25 \times 10^6\text{ J kg}^{-1}Answer
  2. B
    2.25×104 J kg12.25 \times 10^4\text{ J kg}^{-1}
  3. C
    4.50×105 J kg14.50 \times 10^5\text{ J kg}^{-1}
  4. D
    1.25×104 J kg11.25 \times 10^4\text{ J kg}^{-1}

Answer

The specific latent heat of vaporization of the liquid is 2.25×106 J kg12.25 \times 10^6\text{ J kg}^{-1}.
The electrical energy supplied by the heater in 180 seconds180\text{ seconds} is Q=500×180=90,000 JQ = 500 \times 180 = 90,000\text{ J}. Since phase change occurs at constant boiling temperature (100C100^\circ\text{C}), the heat required to vaporize 0.040 kg0.040\text{ kg} of liquid is given by Q=mLvQ = m L_v. Solving for LvL_v yields 90,000 J0.040 kg=2.25×106 J kg1\frac{90,000\text{ J}}{0.040\text{ kg}} = 2.25 \times 10^6\text{ J kg}^{-1}.

Step-by-Step Solution

1
Convert the time duration into seconds
t=3.0 minutes×60 s/min=180 st = 3.0\text{ minutes} \times 60\text{ s/min} = 180\text{ s}
SI units require time to be in seconds when calculating electrical energy.
2
Calculate total electrical thermal energy supplied by the heater
Q=P×t=500 W×180 s=90,000 JQ = P \times t = 500\text{ W} \times 180\text{ s} = 90,000\text{ J}
Thermal energy produced equals power multiplied by time elapsed.
3
Apply the latent heat formula using the mass of liquid vaporized
Lv=Qm=90,000 J0.040 kg=2,250,000 J kg1=2.25×106 J kg1L_v = \frac{Q}{m} = \frac{90,000\text{ J}}{0.040\text{ kg}} = 2,250,000\text{ J kg}^{-1} = 2.25 \times 10^6\text{ J kg}^{-1}
During vaporization at constant boiling temperature, heat energy supplied goes entirely into changing state.

Key Concept

Specific Latent Heat of Vaporization
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