Question

Difficulty: EasyHydrogen: Preparation, Properties, Isotopes, and Water Hardness

Heavy water is water in which the hydrogen atoms are replaced by the hydrogen isotope deuterium (12H^{2}_{1}\text{H} or D\text{D}). Given that the atomic mass of deuterium is 2 g mol12\text{ g mol}^{-1} and oxygen (816O^{16}_{8}\text{O}) is 16 g mol116\text{ g mol}^{-1}, what is the molar mass of heavy water (D2O\text{D}_2\text{O}) in g mol1\text{g mol}^{-1}?

Answer: 20 g mol^-1

Answer

The molar mass of heavy water (D2O\text{D}_2\text{O}) is 20 g mol120\text{ g mol}^{-1}.
Heavy water (D2O\text{D}_2\text{O}) contains two atoms of deuterium (2H^2\text{H}, atomic mass = 22) and one atom of oxygen (16O^{16}\text{O}, atomic mass = 1616). The molar mass is calculated as (2×2)+16=20 g mol1(2 \times 2) + 16 = 20\text{ g mol}^{-1}.

Step-by-Step Solution

1
Determine the molecular composition of heavy water
Heavy water (D2O\text{D}_2\text{O}) contains 2 deuterium atoms and 1 oxygen atom.
Deuterium is an isotope of hydrogen containing one proton and one neutron, giving it a mass number of 2.
2
Sum the relative atomic masses of all constituent atoms
(2×2)+16=20 g mol1(2 \times 2) + 16 = 20\text{ g mol}^{-1}
Multiplying the mass of deuterium by two and adding the mass of one oxygen atom yields the molar mass of the compound.

Key Concept

Heavy Water and Deuterium Molar Mass
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