Question

Difficulty: MediumPostulates of Kinetic Theory and States of Matter

According to the kinetic theory of gases, the average kinetic energy of gas molecules is directly proportional to the absolute temperature. If a sample of nitrogen gas at an initial temperature of 27C27^\circ\text{C} is heated until the average kinetic energy of its molecules is tripled, what is the final temperature of the gas in C^\circ\text{C}?

  1. 627C627^\circ\text{C}Answer
  2. B
    81C81^\circ\text{C}
  3. C
    900C900^\circ\text{C}
  4. D
    1173C1173^\circ\text{C}

Answer

The final temperature of the gas is 627C627^\circ\text{C}.
According to the kinetic theory of gases, the average kinetic energy of gas particles is directly proportional to the absolute temperature in Kelvin (EkTE_k \propto T). Converting the initial temperature 27C27^\circ\text{C} to Kelvin yields 27+273=300 K27 + 273 = 300\text{ K}. Tripling the average kinetic energy means tripling the absolute temperature to 3×300 K=900 K3 \times 300\text{ K} = 900\text{ K}. Converting this back to degrees Celsius gives 900273=627C900 - 273 = 627^\circ\text{C}.

Step-by-Step Solution

1
Convert the initial temperature from Celsius to Kelvin.
T1=27C+273=300 KT_1 = 27^\circ\text{C} + 273 = 300\text{ K}
Kinetic molecular theory states that average kinetic energy is directly proportional to absolute temperature (EkTE_k \propto T in Kelvin).
2
Calculate the new absolute temperature after tripling the kinetic energy.
T2=3×T1=3×300 K=900 KT_2 = 3 \times T_1 = 3 \times 300\text{ K} = 900\text{ K}
Tripling the average kinetic energy directly triples the absolute temperature in Kelvin.
3
Convert the final absolute temperature back to degrees Celsius.
t2=900 K273=627Ct_2 = 900\text{ K} - 273 = 627^\circ\text{C}
The question explicitly requests the final temperature in degrees Celsius (t=T273t = T - 273).

Key Concept

Relationship between average kinetic energy and absolute temperature in the kinetic molecular theory
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