Question

Difficulty: Very hardRadioactive Decay Law and Half-life

A radioactive mixture initially contains two radioisotopes, PP and QQ, such that the initial number of undecayed nuclei of PP is 88 times that of QQ. If the half-life of isotope PP is 2 hours2\text{ hours} and the half-life of isotope QQ is 6 hours6\text{ hours}, calculate the time, in hours, after which the number of undecayed nuclei of both isotopes will be equal.

Answer: 9 hours

Answer

The time after which the number of undecayed nuclei of both isotopes will be equal is 9 hours.
By applying the radioactive decay law N(t)=N0(1/2)t/T1/2N(t) = N_0(1/2)^{t/T_{1/2}} to both isotopes with initial ratio NP0=8NQ0N_{P0} = 8N_{Q0} and equating NP(t)=NQ(t)N_P(t) = N_Q(t), we obtain 8=2t/38 = 2^{t/3}, which gives t=9 hourst = 9\text{ hours}.

Step-by-Step Solution

1
Write the decay equations for isotopes P and Q based on their half-lives
NP(t)=NP0(12)t/2N_P(t) = N_{P0}\left(\frac{1}{2}\right)^{t/2} and NQ(t)=NQ0(12)t/6N_Q(t) = N_{Q0}\left(\frac{1}{2}\right)^{t/6}
Radioactive decay follows the exponential relationship N(t)=N0(12)t/T1/2N(t) = N_0 \left(\frac{1}{2}\right)^{t/T_{1/2}}.
2
Apply the initial condition NP0=8NQ0N_{P0} = 8 N_{Q0} and set the two expressions equal
8NQ0(12)t/2=NQ0(12)t/68 N_{Q0} \left(\frac{1}{2}\right)^{t/2} = N_{Q0} \left(\frac{1}{2}\right)^{t/6}
The problem asks for the time tt when both isotopes have equal remaining undecayed nuclei.
3
Divide both sides by NQ0(12)t/2N_{Q0} \left(\frac{1}{2}\right)^{t/2} and simplify the exponents
8=(1/2)t/6(1/2)t/2=(12)t/3=2t/38 = \frac{(1/2)^{t/6}}{(1/2)^{t/2}} = \left(\frac{1}{2}\right)^{-t/3} = 2^{t/3}
Applying exponent laws simplifies the ratio of powers of one-half into a single base-two exponent.
4
Solve for time tt using powers of 2
23=2t/3    t3=3    t=9 hours2^3 = 2^{t/3} \implies \frac{t}{3} = 3 \implies t = 9\text{ hours}
Equating the exponents of identical base 2 gives the exact time.

Key Concept

Radioactive Decay Law and Half-life for Isotope Mixtures
Estimated Time:2m 0s
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