Question

Difficulty: MediumRelative Atomic Mass, Relative Molecular Mass, and Carbon-12 Scale

A naturally occurring element XX consists of two stable isotopes, 63X^{63}X and 65X^{65}X. If the relative atomic mass of element XX is 63.663.6, what is the percentage abundance of the heavier isotope 65X^{65}X?

  1. 30%30\%Answer
  2. B
    70%70\%
  3. C
    60%60\%
  4. D
    50%50\%

Answer

The percentage abundance of the heavier isotope 65X^{65}X is 30%30\%.
The relative atomic mass of an element with isotopes is calculated using the weighted average formula: RAM=(mass×fractional abundance)\text{RAM} = \sum (\text{mass} \times \text{fractional abundance}). Setting pp as the fraction of 65X^{65}X gives 63.6=63(1p)+65p=63+2p63.6 = 63(1 - p) + 65p = 63 + 2p. Solving yields 2p=0.62p = 0.6, so p=0.30p = 0.30, which corresponds to 30%30\%.

Step-by-Step Solution

1
Set up the relative atomic mass weighted average equation
63.6=(m1×x1)+(m2×x2)10063.6 = \frac{(m_1 \times x_1) + (m_2 \times x_2)}{100}
Relative atomic mass is the weighted average of the atomic masses of naturally occurring isotopes based on their fractional abundances.
2
Express isotopic abundances in terms of a single variable pp
Let pp be the fraction of 65X^{65}X, so the fraction of 63X^{63}X is 1p1 - p.
The sum of the fractional abundances of all isotopes of an element must equal 1 (or 100%100\%).
3
Substitute known values and solve for pp
63.6=63(1p)+65p    63.6=63+2p    2p=0.6    p=0.3063.6 = 63(1 - p) + 65p \implies 63.6 = 63 + 2p \implies 2p = 0.6 \implies p = 0.30
Algebraic expansion isolates the variable corresponding to the heavier isotope abundance.
4
Convert the fractional abundance to percentage
0.30×100%=30%0.30 \times 100\% = 30\%
Multiplying the decimal fraction by 100 yields the percentage abundance.

Key Concept

Calculation of Relative Atomic Mass from Isotopic Abundance
Estimated Time:1m 30s
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