Question

Difficulty: EasySolubility Calculations and Concentration Determination

Calculate the solubility of the salt in the given solution and complete the statement below.

Answer:If 5.85 g5.85\text{ g} of sodium chloride (NaCl\text{NaCl}) is dissolved in water to prepare 250 cm3250\text{ cm}^3 of a saturated solution at 25C25^\circ\text{C}, the solubility of NaCl\text{NaCl} is 【0.4】 mol/dm3\text{mol/dm}^3. [Na=23.0,Cl=35.5][\text{Na} = 23.0, \text{Cl} = 35.5]

Answer

The solubility of sodium chloride at 25C25^\circ\text{C} is 0.4 mol/dm30.4\text{ mol/dm}^3.
The solubility in mol/dm3\text{mol/dm}^3 is obtained by dividing the moles of solute by the solution volume in dm3\text{dm}^3. Here, 5.85 g5.85\text{ g} of NaCl\text{NaCl} corresponds to 0.1 mol0.1\text{ mol} (5.85/58.55.85 / 58.5), and 250 cm3250\text{ cm}^3 equals 0.25 dm30.25\text{ dm}^3. Dividing 0.1 mol0.1\text{ mol} by 0.25 dm30.25\text{ dm}^3 gives 0.4 mol/dm30.4\text{ mol/dm}^3.

Step-by-Step Solution

1
Calculate the molar mass of sodium chloride (NaCl\text{NaCl}).
Molar mass =23.0+35.5=58.5 g/mol= 23.0 + 35.5 = 58.5\text{ g/mol}.
The molar mass is required to convert mass in grams to amount in moles.
2
Determine the number of moles of NaCl\text{NaCl} present.
Moles=5.85 g58.5 g/mol=0.1 mol\text{Moles} = \frac{5.85\text{ g}}{58.5\text{ g/mol}} = 0.1\text{ mol}.
Solubility in mol/dm3\text{mol/dm}^3 requires the quantity of solute in moles.
3
Convert the volume of solution from cm3\text{cm}^3 to dm3\text{dm}^3.
Volume=250 cm31000=0.25 dm3\text{Volume} = \frac{250\text{ cm}^3}{1000} = 0.25\text{ dm}^3.
Concentration units are per cubic decimeter (dm3\text{dm}^3).
4
Calculate the molar concentration (solubility).
Solubility=0.1 mol0.25 dm3=0.4 mol/dm3\text{Solubility} = \frac{0.1\text{ mol}}{0.25\text{ dm}^3} = 0.4\text{ mol/dm}^3.
Solubility is calculated as moles of solute divided by volume of solution in dm3\text{dm}^3.

Key Concept

Solubility and Concentration Determination
Estimated Time:45s
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