Question

Difficulty: MediumBoyle's Law and Pressure-Volume Relationship

A fixed mass of gas occupies a volume of 800 cm3800\text{ cm}^3 at a pressure of 1.5 atm1.5\text{ atm} under isothermal conditions. What is the final volume of the gas in cm3\text{cm}^3 if the pressure is reduced to 570 mmHg570\text{ mmHg}? (1 atm=760 mmHg1\text{ atm} = 760\text{ mmHg})

  1. 1600 cm31600\text{ cm}^3Answer
  2. B
    400 cm3400\text{ cm}^3
  3. C
    2.11 cm32.11\text{ cm}^3
  4. D
    22400 cm322400\text{ cm}^3

Answer

The final volume of the gas is 1600 cm31600\text{ cm}^3.
Under isothermal conditions, Boyle's Law applies (P1V1=P2V2P_1V_1 = P_2V_2). Converting the initial pressure of 1.5 atm1.5\text{ atm} to mmHg\text{mmHg} gives 1140 mmHg1140\text{ mmHg}. Substituting the values into 1140×800=570×V21140 \times 800 = 570 \times V_2 yields V2=1600 cm3V_2 = 1600\text{ cm}^3.

Step-by-Step Solution

1
Convert the initial pressure (P1P_1) to the same unit as the final pressure (P2P_2).
P1=1.5 atm×760 mmHg/atm=1140 mmHgP_1 = 1.5\text{ atm} \times 760\text{ mmHg/atm} = 1140\text{ mmHg}.
Units of pressure must be consistent before applying gas law equations.
2
Apply Boyle's Law formula for isothermal conditions.
P1V1=P2V2    1140 mmHg×800 cm3=570 mmHg×V2P_1V_1 = P_2V_2 \implies 1140\text{ mmHg} \times 800\text{ cm}^3 = 570\text{ mmHg} \times V_2.
Boyle's Law states that for a fixed mass of gas at constant temperature, pressure and volume are inversely proportional.
3
Rearrange the equation to solve for V2V_2.
V2=1140×800570=1600 cm3V_2 = \frac{1140 \times 800}{570} = 1600\text{ cm}^3.
Calculates the expanded volume resulting from the decrease in pressure.

Key Concept

Boyle's Law (P1V1=P2V2P_1V_1 = P_2V_2 at constant temperature)
Estimated Time:1m 30s
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