Question

Difficulty: MediumGas Laws and the Ideal Gas Equation

An air bubble with an initial volume of 4.0 cm34.0\text{ cm}^3 is released by a scuba diver at a depth where the total pressure is 2.50×105 Pa2.50 \times 10^5\text{ Pa} and the water temperature is 7C7^\circ\text{C}. Calculate the volume of the bubble, in cm3\text{cm}^3, just as it reaches the surface where the pressure is 1.00×105 Pa1.00 \times 10^5\text{ Pa} and the water temperature is 77C77^\circ\text{C}.

Answer: 12.5 cm³

Answer

12.5 cm³
Converting temperatures to the Kelvin scale (T1=280 KT_1 = 280\text{ K} and T2=350 KT_2 = 350\text{ K}) and applying the combined gas law formula P1V1T1=P2V2T2\frac{P_1 V_1}{T_1} = \frac{P_2 V_2}{T_2} gives a final volume of 12.5 cm312.5\text{ cm}^3.

Step-by-Step Solution

1
Convert the initial and final temperatures from degrees Celsius to absolute temperatures in Kelvin.
T1=7C+273=280 KT_1 = 7^\circ\text{C} + 273 = 280\text{ K} and T2=77C+273=350 KT_2 = 77^\circ\text{C} + 273 = 350\text{ K}.
Gas law calculations require thermodynamic temperature measured on the Kelvin scale.
2
Set up the combined gas law relationship for a fixed mass of gas.
P1V1T1=P2V2T2\frac{P_1 V_1}{T_1} = \frac{P_2 V_2}{T_2}
The mass of air inside the bubble remains constant while pressure, volume, and temperature change simultaneously.
3
Substitute the known values into the equation and solve for the final volume V2V_2.
V2=P1V1T2P2T1=(2.50×105 Pa)×(4.0 cm3)×(350 K)(1.00×105 Pa)×(280 K)=12.5 cm3V_2 = \frac{P_1 V_1 T_2}{P_2 T_1} = \frac{(2.50 \times 10^5\text{ Pa}) \times (4.0\text{ cm}^3) \times (350\text{ K})}{(1.00 \times 10^5\text{ Pa}) \times (280\text{ K})} = 12.5\text{ cm}^3.
Algebraic substitution yields the correct final volume of the expanded bubble.

Key Concept

Combined Gas Law
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