Question

Difficulty: MediumCharles's Law and Absolute Temperature Scale

Match each condition or graphical representation of a gas sample obeying Charles's law with its corresponding physical or mathematical outcome.

  • A gas sample is heated from 27C27^\circ\text{C} to 54C54^\circ\text{C} at constant pressureVolume increases by a factor of 1.091.09
  • A gas sample is heated from 300 K300\text{ K} to 600 K600\text{ K} at constant pressureVolume doubles (V2=2V1V_2 = 2V_1)
  • Extrapolation of a volume versus temperature (C^\circ\text{C}) plot to zero volumeIntersects the temperature axis at absolute zero (273C-273^\circ\text{C})
  • Plot of volume (VV) versus absolute temperature (TT in K\text{K}) at constant pressureStraight line passing through the origin

Answer

The correct pairings match heating from 27 °C to 54 °C with a volume increase factor of 1.09, heating from 300 K to 600 K with volume doubling, extrapolation to zero volume with intersecting the temperature axis at absolute zero (-273 °C), and the V versus T (K) plot with a straight line through the origin.
Each item correctly links a concept of Charles's law to its outcome: heating from 27C27^\circ\text{C} (300 K300\text{ K}) to 54C54^\circ\text{C} (327 K327\text{ K}) increases volume by a factor of 1.091.09; heating from 300 K300\text{ K} to 600 K600\text{ K} doubles absolute temperature and volume; extrapolating a VV-TT (C^\circ\text{C}) graph to zero volume yields absolute zero (273C-273^\circ\text{C}); and plotting VV against absolute temperature (TT in K\text{K}) produces a straight line passing through the origin.

Step-by-Step Solution

1
Convert Celsius temperatures to Kelvin for the first scenario
T1=27+273=300 KT_1 = 27 + 273 = 300\text{ K} and T2=54+273=327 KT_2 = 54 + 273 = 327\text{ K}.
Charles's law requires temperatures to be expressed in Kelvin.
2
Determine the volume ratio for heating from 27C27^\circ\text{C} to 54C54^\circ\text{C}
\frac{V_2}{V_1} = \frac{T_2}{T_1} = \frac{327\text{ K}}{300\text{ K}} = 1.09.
Doubling Celsius temperature does not double absolute temperature, so volume increases by a factor of 1.09.
3
Apply direct proportionality for the Kelvin heating scenario
Heating from 300 K300\text{ K} to 600 K600\text{ K} doubles the absolute temperature, so V2=2V1V_2 = 2V_1.
Volume is directly proportional to temperature on the Kelvin scale.
4
Analyze graphical characteristics of Charles's law
A VV vs TT (K) plot is a straight line through the origin (0,0)(0,0), and extrapolating VV vs TT (C^\circ\text{C}) to zero volume yields absolute zero (273C-273^\circ\text{C}).
Absolute zero is the theoretical temperature at which gas volume extrapolates to zero.

Key Concept

Charles's Law and Absolute Temperature Scale
Estimated Time:1m 30s
Rate this question