Question

Difficulty: MediumThe Mole Concept, Avogadro's Constant, and Molar Mass

What is the total number of ions present in a 9.5 g9.5\text{ g} sample of pure magnesium chloride (MgCl2\text{MgCl}_2)? [Mg=24,Cl=35.5,NA=6.02×1023 mol1][\text{Mg} = 24, \text{Cl} = 35.5, N_A = 6.02 \times 10^{23}\text{ mol}^{-1}]

  1. 1.81×10231.81 \times 10^{23}Answer
  2. B
    6.02×10226.02 \times 10^{22}
  3. C
    1.20×10231.20 \times 10^{23}
  4. D
    2.24×10232.24 \times 10^{23}

Answer

1.81×10231.81 \times 10^{23} ions
The sample contains 0.1 mol0.1\text{ mol} of MgCl2\text{MgCl}_2. Because each formula unit of MgCl2\text{MgCl}_2 dissociates into 3 ions (1 Mg2+1\text{ Mg}^{2+} and 2 Cl2\text{ Cl}^-), there are 0.3 mol0.3\text{ mol} of total ions. Multiplying 0.3 mol0.3\text{ mol} by Avogadro's constant (6.02×10236.02 \times 10^{23}) yields 1.81×10231.81 \times 10^{23} ions.

Step-by-Step Solution

1
Calculate the molar mass of magnesium chloride (MgCl2\text{MgCl}_2)
Molar mass =24+2(35.5)=95 g/mol= 24 + 2(35.5) = 95\text{ g/mol}
Molar mass is required to convert the given mass into moles.
2
Determine the number of moles of MgCl2\text{MgCl}_2 in 9.5 g9.5\text{ g}
Moles =9.5 g/95 g/mol=0.1 mol= 9.5\text{ g} / 95\text{ g/mol} = 0.1\text{ mol}
Applying the mole formula: moles=mass/molar mass\text{moles} = \text{mass} / \text{molar mass}.
3
Determine the total moles of ions released upon dissociation
MgCl2Mg2++2Cl\text{MgCl}_2 \rightarrow \text{Mg}^{2+} + 2\text{Cl}^-, giving 3 moles of ions per mole of salt. Total ion moles =0.1×3=0.3 mol= 0.1 \times 3 = 0.3\text{ mol}
Each formula unit of magnesium chloride contains one magnesium ion and two chloride ions.
4
Calculate the total number of individual ions using Avogadro's constant
Total ions =0.3×6.02×1023=1.806×10231.81×1023= 0.3 \times 6.02 \times 10^{23} = 1.806 \times 10^{23} \approx 1.81 \times 10^{23} ions
Multiplying the total moles of ions by Avogadro's constant yields particle count.

Key Concept

The Mole Concept and Avogadro's Constant applied to Ionic Dissociation
Estimated Time:1m 30s
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