Question

Difficulty: MediumTemperature Scales and Thermometric Properties

A thermocouple thermometer produces an electromotive force (e.m.f.) of 2.0 mV2.0\,\text{mV} at the ice point (0∘C0^\circ\text{C}) and 18.0 mV18.0\,\text{mV} at the steam point (100∘C100^\circ\text{C}). When placed in a liquid bath, the recorded e.m.f. is 14.0 mV14.0\,\text{mV}. What is the temperature of the liquid bath on the Celsius scale?

  1. A
    66.7∘C66.7^\circ\text{C}
  2. B
    70.0∘C70.0^\circ\text{C}
  3. 75.0∘C75.0^\circ\text{C}Answer
  4. D
    87.5∘C87.5^\circ\text{C}

Answer

75.0∘C75.0^\circ\text{C}
The temperature on a linear scale is proportional to the fraction of the interval traversed between the fixed points. Subtracting the baseline reading of 2.0 mV2.0\,\text{mV} gives an effective increase of 12.0 mV12.0\,\text{mV} out of a total range of 16.0 mV16.0\,\text{mV}. Multiplying this fraction (0.750.75) by 100∘C100^\circ\text{C} yields 75.0∘C75.0^\circ\text{C}.

Step-by-Step Solution

1
Identify the given thermometric values for the lower fixed point, upper fixed point, and unknown temperature reading.
E0=2.0 mVE_0 = 2.0\,\text{mV}, E100=18.0 mVE_{100} = 18.0\,\text{mV}, and Eθ=14.0 mVE_\theta = 14.0\,\text{mV}.
Linear temperature scales relate the change in thermometric property proportionally to temperature changes.
2
Apply the standard linear interpolation formula for a Celsius temperature scale.
θ=Eθ−E0E100−E0×100∘C\theta = \frac{E_\theta - E_0}{E_{100} - E_0} \times 100^\circ\text{C}
This accounts for the baseline reading at the ice point (0∘C0^\circ\text{C}) and normalizes it over the 100∘C100^\circ\text{C} fundamental interval.
3
Substitute the known values and evaluate the expression.
θ=14.0−2.018.0−2.0×100=12.016.0×100=0.75×100=75.0∘C\theta = \frac{14.0 - 2.0}{18.0 - 2.0} \times 100 = \frac{12.0}{16.0} \times 100 = 0.75 \times 100 = 75.0^\circ\text{C}.
Carrying out the subtraction yields a proportional change of 34\frac{3}{4} of the full fundamental interval.

Key Concept

Temperature Scale Calibration and Thermocouple Interpolation
Estimated Time:1m 30s
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