Atmospheric pollution by industrial emissions can lead to terrestrial ecosystem degradation through acid deposition. Arrange the following sequential steps in the correct order to illustrate how acid rain forms and subsequently causes forest decline, starting from initial pollutant emission to final biological effect.
- 1Emission of sulfur dioxide () and nitrogen oxides () from industrial combustion into the atmosphere.
- 2Atmospheric reaction of emitted gases with water vapor and oxygen to form sulfuric acid () and nitric acid ().
- 3Precipitation of acidic moisture onto soil, significantly lowering the terrestrial soil pH.
- 4Mobilization of toxic aluminum ions () and leaching of essential plant nutrients like calcium and magnesium from the soil.
- 5Uptake of toxic ions and loss of nutrients causing root damage, impaired water absorption, leaf chlorosis, and eventual tree dieback.
Answer
The correct order of events begins with the emission of and primary pollutants into the atmosphere, followed by their atmospheric oxidation to sulfuric and nitric acids, acid precipitation onto forest soil, mobilization of toxic aluminum ions with leaching of essential plant nutrients, and finally root damage causing leaf chlorosis and tree dieback.
Acid deposition follows a direct cause-and-effect cascade: Primary industrial gas emissions (, ) undergo atmospheric oxidation into secondary acids (, ). When acid rain falls, it acidifies soil water, which mobilizes phytotoxic ions and washes away nutrient cations (, ). The resulting nutrient starvation and root cytotoxicity lead directly to chlorosis and forest dieback.
Step-by-Step Solution
Key Concept
Acid deposition sequence, cause-and-effect mechanisms of atmospheric pollution on soil chemistry and plant physiology