Thermal Physics

170 questions

Question 61Question

A resistance thermometer registers a resistance of 5.0Ω5.0\,\Omega at the ice point (0C0^\circ\text{C}) and 25.0Ω25.0\,\Omega at the steam point (100C100^\circ\text{C}). When placed in a heated liquid bath, the resistance measured is 30.0Ω30.0\,\Omega. What is the temperature of the bath on the Kelvin scale?

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Answer: 398K398\,\text{K}

Answer

The temperature of the bath on the Kelvin scale is 398K398\,\text{K}.
Using the linear interpolation formula for a thermometric property θ=RθR0R100R0×100C\theta = \frac{R_\theta - R_0}{R_{100} - R_0} \times 100^\circ\text{C}, substituting R0=5.0ΩR_0 = 5.0\,\Omega, R100=25.0ΩR_{100} = 25.0\,\Omega, and Rθ=30.0ΩR_\theta = 30.0\,\Omega yields θ=25.020.0×100=125C\theta = \frac{25.0}{20.0} \times 100 = 125^\circ\text{C}. Converting to absolute thermodynamic temperature gives T=125+273=398KT = 125 + 273 = 398\,\text{K}.

Step-by-Step Solution

1
Calculate the temperature on the Celsius scale using linear interpolation of thermometric property.
θ=RθR0R100R0×100C=30.05.025.05.0×100C=25.020.0×100C=125C\theta = \frac{R_\theta - R_0}{R_{100} - R_0} \times 100^\circ\text{C} = \frac{30.0 - 5.0}{25.0 - 5.0} \times 100^\circ\text{C} = \frac{25.0}{20.0} \times 100^\circ\text{C} = 125^\circ\text{C}
The change in resistance is directly proportional to the temperature change between fixed points.
2
Convert the temperature from degrees Celsius to Kelvins.
T=θ+273=125+273=398KT = \theta + 273 = 125 + 273 = 398\,\text{K}
Absolute temperature in Kelvin is obtained by adding 273 to the temperature in degrees Celsius.

Key Concept

Temperature Scale Interpolation and Kelvin Conversion
Estimated Time:1m 30s
Question 62Question

The length of the mercury column in an uncalibrated thermometer is 4.0cm4.0\,\text{cm} at the ice point (0C0^\circ\text{C}) and 24.0cm24.0\,\text{cm} at the steam point (100C100^\circ\text{C}). What is the temperature in degrees Celsius when the length of the mercury column is 19.0cm19.0\,\text{cm}?

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Answer: 75

Answer

The temperature corresponding to a mercury column length of 19.0cm19.0\,\text{cm} is 75C75^\circ\text{C}.
The temperature on the Celsius scale is determined by the ratio of the length change above the ice point to the total length change between the ice and steam points: T=LTL0L100L0×100CT = \frac{L_T - L_0}{L_{100} - L_0} \times 100^\circ\text{C}. Substituting L0=4.0cmL_0 = 4.0\,\text{cm}, L100=24.0cmL_{100} = 24.0\,\text{cm}, and LT=19.0cmL_T = 19.0\,\text{cm} gives T=15.020.0×100=75CT = \frac{15.0}{20.0} \times 100 = 75^\circ\text{C}.

Step-by-Step Solution

1
Identify given thermometric length values at fixed points and at the unknown temperature
L0=4.0cmL_0 = 4.0\,\text{cm}, L100=24.0cmL_{100} = 24.0\,\text{cm}, and LT=19.0cmL_T = 19.0\,\text{cm}
These represent the length at the lower fixed point (0C0^\circ\text{C}), upper fixed point (100C100^\circ\text{C}), and intermediate temperature TT respectively.
2
Set up the linear interpolation equation on the Celsius scale
T=LTL0L100L0×100CT = \frac{L_T - L_0}{L_{100} - L_0} \times 100^\circ\text{C}
Thermometric expansion is assumed to vary linearly with temperature over the operational range.
3
Substitute the given values and perform arithmetic calculation
T=19.04.024.04.0×100=15.020.0×100=75CT = \frac{19.0 - 4.0}{24.0 - 4.0} \times 100 = \frac{15.0}{20.0} \times 100 = 75^\circ\text{C}
Simplifying 15.020.0\frac{15.0}{20.0} gives 0.750.75, which multiplied by 100100 equals 7575.

Key Concept

Temperature measurement using linear variation of thermometric properties
Question 63Question

An aluminium rod of initial length 2.0 m2.0\text{ m} at 20C20^\circ\text{C} expands by 0.96 mm0.96\text{ mm} when heated. If the linear expansivity of aluminium is 2.4×105 K12.4 \times 10^{-5}\text{ K}^{-1}, what is the rise in temperature of the rod?

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Answer: 20

Answer

The rise in temperature of the aluminium rod is 20 K20\text{ K}.
The fractional change in length depends on linear expansivity and temperature change through ΔL=L0αΔT\Delta L = L_0 \alpha \Delta T. Substituting the converted expansion ΔL=9.6×104 m\Delta L = 9.6 \times 10^{-4}\text{ m}, initial length L0=2.0 mL_0 = 2.0\text{ m}, and linear expansivity α=2.4×105 K1\alpha = 2.4 \times 10^{-5}\text{ K}^{-1} gives ΔT=9.6×1042.0×2.4×105=20 K\Delta T = \frac{9.6 \times 10^{-4}}{2.0 \times 2.4 \times 10^{-5}} = 20\text{ K}.

Step-by-Step Solution

1
Convert change in length from millimeters to meters
\Delta L = 9.6 \times 10^{-4}\text{ m}
Units must be consistent with initial length in meters.
2
Rearrange the linear thermal expansion formula \Delta L = L_0 \alpha \Delta T for temperature change \Delta T
\Delta T = \frac{\Delta L}{L_0 \alpha}
To isolate the unknown quantity \Delta T.
3
Substitute values into the rearranged formula and compute \Delta T
\Delta T = \frac{9.6 \times 10^{-4}}{2.0 \times (2.4 \times 10^{-5})} = 20\text{ K}
Evaluating the mathematical expression yields the required temperature rise.

Key Concept

Linear Expansivity and Thermal Expansion of Solids
Question 64Question

A glass flask of volume 1000 cm31000\text{ cm}^3 is filled completely with mercury at a temperature of 10C10^\circ\text{C}. The linear expansivity of the glass is 9.0×106 K19.0 \times 10^{-6}\text{ K}^{-1} and the real cubic expansivity of mercury is 1.8×104 K11.8 \times 10^{-4}\text{ K}^{-1}. What volume of mercury (in cm3\text{cm}^3) will overflow when the system is heated to 110C110^\circ\text{C}?

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Answer: 15.3

Answer

The volume of mercury that overflows is 15.3 cm315.3\text{ cm}^3.
The apparent expansion of the liquid equals its real expansion minus the expansion of the container. Since γv=3α=2.7×105 K1=0.27×104 K1\gamma_v = 3\alpha = 2.7 \times 10^{-5}\text{ K}^{-1} = 0.27 \times 10^{-4}\text{ K}^{-1}, the apparent cubic expansivity is γa=1.8×1040.27×104=1.53×104 K1\gamma_a = 1.8 \times 10^{-4} - 0.27 \times 10^{-4} = 1.53 \times 10^{-4}\text{ K}^{-1}. Multiplying by initial volume (1000 cm31000\text{ cm}^3) and temperature change (100 K100\text{ K}) yields an overflow volume of 15.3 cm315.3\text{ cm}^3.

Step-by-Step Solution

1
Calculate the volume expansivity of the glass vessel (γv\gamma_v)
γv=3×9.0×106 K1=2.7×105 K1=0.27×104 K1\gamma_v = 3 \times 9.0 \times 10^{-6}\text{ K}^{-1} = 2.7 \times 10^{-5}\text{ K}^{-1} = 0.27 \times 10^{-4}\text{ K}^{-1}
The volumetric (cubic) expansivity of a solid container is three times its linear expansivity.
2
Determine the apparent cubic expansivity of mercury (γa\gamma_a)
γa=γrγv=1.8×1040.27×104=1.53×104 K1\gamma_a = \gamma_r - \gamma_v = 1.8 \times 10^{-4} - 0.27 \times 10^{-4} = 1.53 \times 10^{-4}\text{ K}^{-1}
The apparent expansion of a liquid accounts for both the expansion of the liquid itself and the expansion of the containing vessel.
3
Calculate the overflow volume (apparent expansion ΔVa\Delta V_a)
\Delta V_a = V_0 \times \gamma_a \times \Delta T = 1000 \times 1.53 \times 10^{-4} \times 100 = 15.3\text{ cm}^3
The volume of liquid that overflows corresponds directly to its apparent volume increase.

Key Concept

Real and Apparent Cubical Expansivity of Liquids
Estimated Time:1m 30s
Question 65Question

A railway line is laid using steel rails, each of length 15 m15\text{ m}, at a temperature of 20C20^\circ\text{C}. What minimum gap, in millimetres (mm\text{mm}), must be left between consecutive rails so that they just touch without buckling when heated to 60C60^\circ\text{C}? [Linear expansivity of steel = 1.2×105 K11.2 \times 10^{-5}\text{ K}^{-1}]

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Answer: 7.2

Answer

The minimum gap required between consecutive rails is 7.2 mm7.2\text{ mm}.
The expansion in length ΔL\Delta L is given by ΔL=L0αΔT\Delta L = L_0 \alpha \Delta T. Substituting the initial length L0=15 mL_0 = 15\text{ m}, linear expansivity α=1.2×105 K1\alpha = 1.2 \times 10^{-5}\text{ K}^{-1}, and temperature change ΔT=40 K\Delta T = 40\text{ K} gives ΔL=7.2×103 m\Delta L = 7.2 \times 10^{-3}\text{ m}, which corresponds to 7.2 mm7.2\text{ mm}.

Step-by-Step Solution

1
Determine the change in temperature
\Delta T = 60^\circ\text{C} - 20^\circ\text{C} = 40\text{ K}
Thermal expansion is driven by the temperature difference between the final and initial states.
2
Set up the linear expansion formula
\Delta L = L_0 \alpha \Delta T
The linear expansion of a solid bar depends on its initial length, the material's linear expansivity, and the temperature change.
3
Calculate the expansion in metres and convert to millimetres
\Delta L = 15 \times (1.2 \times 10^{-5}) \times 40 = 7.2 \times 10^{-3}\text{ m} = 7.2\text{ mm}
Multiplying the value in metres by 10001000 yields the required measurement in millimetres.

Key Concept

Linear Expansivity and Thermal Expansion of Solids
Estimated Time:1m 30s
Question 66Question

A brass container with an initial capacity of 500 cm3500\text{ cm}^3 at 20C20^\circ\text{C} is filled completely with ethanol. When the container and its contents are uniformly heated to 70C70^\circ\text{C}, a volume of 12 cm312\text{ cm}^3 of ethanol overflows from the container. Given that the linear expansivity of brass is 2.0×105 K12.0 \times 10^{-5}\text{ K}^{-1}, calculate the real cubic expansivity of ethanol in units of 104 K110^{-4}\text{ K}^{-1}.

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Answer: 5.4

Answer

The real cubic expansivity of ethanol is 5.4×104 K15.4 \times 10^{-4}\text{ K}^{-1}, which corresponds to a value of 5.45.4 in units of 104 K110^{-4}\text{ K}^{-1}.
The real volume increase of a liquid consists of the apparent expansion (observed overflow volume) plus the volume expansion of the container itself. By finding the apparent cubic expansivity γa=12500×50=4.8×104 K1\gamma_a = \frac{12}{500 \times 50} = 4.8 \times 10^{-4}\text{ K}^{-1} and adding the vessel's cubic expansivity γv=3×2.0×105=0.6×104 K1\gamma_v = 3 \times 2.0 \times 10^{-5} = 0.6 \times 10^{-4}\text{ K}^{-1}, we obtain the real cubic expansivity γr=5.4×104 K1\gamma_r = 5.4 \times 10^{-4}\text{ K}^{-1}, which yields 5.45.4 in the required units.

Step-by-Step Solution

1
Determine the temperature increase of the system
\Delta T = 70^\circ\text{C} - 20^\circ\text{C} = 50\text{ K}
The thermal expansion is driven by the change in temperature.
2
Calculate the apparent cubic expansivity of ethanol (\gamma_a)
\gamma_a = \frac{\Delta V_{overflow}}{V_0 \cdot \Delta T} = \frac{12\text{ cm}^3}{500\text{ cm}^3 \times 50\text{ K}} = 4.8 \times 10^{-4}\text{ K}^{-1}
The overflow volume represents the apparent volume increase of the liquid relative to the expanding vessel.
3
Calculate the cubic expansivity of the brass vessel (\gamma_v)
\gamma_v = 3 \times \alpha_{brass} = 3 \times 2.0 \times 10^{-5}\text{ K}^{-1} = 6.0 \times 10^{-5}\text{ K}^{-1} = 0.6 \times 10^{-4}\text{ K}^{-1}
Cubic expansivity of a solid vessel is three times its linear expansivity.
4
Compute the real cubic expansivity of ethanol (\gamma_r)
\gamma_r = \gamma_a + \gamma_v = 4.8 \times 10^{-4}\text{ K}^{-1} + 0.6 \times 10^{-4}\text{ K}^{-1} = 5.4 \times 10^{-4}\text{ K}^{-1}
The real expansion of a liquid is the sum of its apparent expansion and the expansion of the containing vessel.

Key Concept

Relationship between Real and Apparent Cubic Expansivity of Liquids
Question 67Question

A solid metal block of mass 4.0 kg4.0\text{ kg} has a density of 8000 kg m38000\text{ kg m}^{-3} at 20C20^\circ\text{C}. If the linear expansivity of the metal is 2.0×105 K12.0 \times 10^{-5}\text{ K}^{-1}, calculate the increase in volume of the block, in cm3\text{cm}^3, when its temperature is raised to 120C120^\circ\text{C}.

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Answer: 3

Answer

The increase in volume of the block is 3.0 cm33.0\text{ cm}^3.
First, the initial volume of the metal block is found using V0=mρ=4.0 kg8000 kg m3=5.0×104 m3=500 cm3V_0 = \frac{m}{\rho} = \frac{4.0\text{ kg}}{8000\text{ kg m}^{-3}} = 5.0 \times 10^{-4}\text{ m}^3 = 500\text{ cm}^3. Next, because a solid expands in three dimensions, the cubic expansivity is γ=3α=3×(2.0×105 K1)=6.0×105 K1\gamma = 3\alpha = 3 \times (2.0 \times 10^{-5}\text{ K}^{-1}) = 6.0 \times 10^{-5}\text{ K}^{-1}. The temperature change is ΔT=120C20C=100 K\Delta T = 120^\circ\text{C} - 20^\circ\text{C} = 100\text{ K}. Finally, the increase in volume is computed as ΔV=V0γΔT=500 cm3×(6.0×105 K1)×100 K=3.0 cm3\Delta V = V_0 \gamma \Delta T = 500\text{ cm}^3 \times (6.0 \times 10^{-5}\text{ K}^{-1}) \times 100\text{ K} = 3.0\text{ cm}^3.

Step-by-Step Solution

1
Calculate the initial volume of the metal block from its mass and density.
V0=mρ0=4.0 kg8000 kg m3=5.0×104 m3=500 cm3V_0 = \frac{m}{\rho_0} = \frac{4.0\text{ kg}}{8000\text{ kg m}^{-3}} = 5.0 \times 10^{-4}\text{ m}^3 = 500\text{ cm}^3
Volume is equal to mass divided by density.
2
Convert linear expansivity (α\alpha) to volume expansivity (γ\gamma).
γ=3α=3×(2.0×105 K1)=6.0×105 K1\gamma = 3\alpha = 3 \times (2.0 \times 10^{-5}\text{ K}^{-1}) = 6.0 \times 10^{-5}\text{ K}^{-1}
For an isotropic solid, cubic expansivity is three times its linear expansivity.
3
Determine the change in temperature.
ΔT=120C20C=100 K\Delta T = 120^\circ\text{C} - 20^\circ\text{C} = 100\text{ K}
Thermal expansion is driven by the change in temperature.
4
Calculate the total volume expansion.
ΔV=V0γΔT=500 cm3×(6.0×105 K1)×100 K=3.0 cm3\Delta V = V_0 \gamma \Delta T = 500\text{ cm}^3 \times (6.0 \times 10^{-5}\text{ K}^{-1}) \times 100\text{ K} = 3.0\text{ cm}^3
Applying the thermal volume expansion formula ΔV=V0γΔT\Delta V = V_0 \gamma \Delta T.

Key Concept

Thermal Volume Expansion of Solids
Estimated Time:2m 0s
Question 68Question

A faulty liquid-in-glass thermometer registers a reading of 5C5^\circ\text{C} at the melting ice point and 95C95^\circ\text{C} at the steam point of pure water under standard atmospheric pressure. What is the actual temperature in degrees Celsius when this thermometer registers a reading of 41C41^\circ\text{C}?

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Answer: 40C40^\circ\text{C}

Answer

The actual temperature is 40C40^\circ\text{C}.
The correct answer is obtained by setting up the linear interpolation formula for thermometric property values: θ=XθX0X100X0×100\theta = \frac{X_\theta - X_0}{X_{100} - X_0} \times 100. Substituting X0=5X_0 = 5, X100=95X_{100} = 95, and Xθ=41X_\theta = 41 gives θ=3690×100=40C\theta = \frac{36}{90} \times 100 = 40^\circ\text{C}.

Step-by-Step Solution

1
Determine the fundamental interval of the faulty thermometer.
Fundamental interval =95C5C=90divisions= 95^\circ\text{C} - 5^\circ\text{C} = 90\,\text{divisions}.
The total interval between the lower fixed point and upper fixed point represents 100C100^\circ\text{C} on the standard Celsius scale.
2
Calculate the measured change from the ice point.
Measured difference =41C5C=36divisions= 41^\circ\text{C} - 5^\circ\text{C} = 36\,\text{divisions}.
The zero error of +5C+5^\circ\text{C} must be subtracted from the observed reading.
3
Apply the linear scale interpolation formula to find the actual temperature θ\theta.
θ=415955×100C=3690×100C=40C\theta = \frac{41 - 5}{95 - 5} \times 100^\circ\text{C} = \frac{36}{90} \times 100^\circ\text{C} = 40^\circ\text{C}.
The ratio of the measured interval to the total fundamental interval equals the true fraction of 100C100^\circ\text{C}.

Key Concept

Linear interpolation on non-standard or faulty thermometer scales using fixed points.
Question 69Question

A metal container with an initial volume of 500 cm3500\text{ cm}^3 is completely filled with an organic liquid at 15C15^\circ\text{C}. The real cubic expansivity of the liquid is 4.0×104 K14.0 \times 10^{-4}\text{ K}^{-1}. When the container and liquid are heated together to a final temperature of 65C65^\circ\text{C}, exactly 8.5 cm38.5\text{ cm}^3 of the liquid overflows. What is the linear expansivity of the metal container, in units of 105 K110^{-5}\text{ K}^{-1}?

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Answer: 2

Answer

The linear expansivity of the metal container is 2.0×105 K12.0 \times 10^{-5}\text{ K}^{-1}, which corresponds to a numerical value of 2.02.0 in units of 105 K110^{-5}\text{ K}^{-1}.
The apparent expansivity of the liquid is derived from the overflow volume (8.5 cm^3 / (500 cm^3 * 50 K) = 3.4 x 10^-4 K^-1). Subtracting this from the liquid's real expansivity (4.0 x 10^-4 K^-1) yields the container's cubic expansivity of 0.6 x 10^-4 K^-1 (or 6.0 x 10^-5 K^-1). Dividing by 3 gives the linear expansivity of the container material as 2.0 x 10^-5 K^-1.

Step-by-Step Solution

1
Determine the temperature increase
\Delta T = 50\text{ K}
Temperature change drives the thermal expansion process.
2
Compute the apparent cubic expansivity of the liquid
\gamma_a = 3.4 \times 10^{-4}\text{ K}^{-1}
Apparent expansion is measured directly from the liquid overflow relative to initial volume and temperature rise.
3
Calculate the cubic expansivity of the metal container
\gamma_v = 6.0 \times 10^{-5}\text{ K}^{-1}
The difference between real cubic expansivity of the liquid and its apparent cubic expansivity equals the cubic expansivity of the container.
4
Calculate the linear expansivity of the container material
\alpha = 2.0 \times 10^{-5}\text{ K}^{-1}
For isotropic solids, volume expansivity is three times linear expansivity (\gamma_v = 3\alpha).

Key Concept

Thermal expansion of liquids in expanding vessels: Real expansivity equals apparent expansivity plus vessel cubic expansivity (\gamma_r = \gamma_a + 3\alpha).
Estimated Time:2m 0s
Question 70Question

A platinum resistance thermometer has a resistance of 10Ω10\,\Omega at the ice point (0C0^\circ\text{C}) and 50Ω50\,\Omega at the steam point (100C100^\circ\text{C}). When placed in a warm liquid bath, an uncalibrated digital ohmmeter reads 38Ω38\,\Omega. If the ohmmeter has a known positive zero error of +4Ω+4\,\Omega (indicating 4Ω4\,\Omega above the true resistance), what is the actual temperature of the liquid bath on the absolute scale in kelvins?

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Answer: 333K333\,\text{K}

Answer

The actual temperature of the liquid bath on the absolute scale is 333K333\,\text{K}.
Subtracting the zero error of +4Ω+4\,\Omega from the raw meter reading of 38Ω38\,\Omega yields the true thermometric resistance of 34Ω34\,\Omega. Applying the temperature formula θ=RθR0R100R0×100C\theta = \frac{R_\theta - R_0}{R_{100} - R_0} \times 100^\circ\text{C} gives θ=34105010×100=60C\theta = \frac{34 - 10}{50 - 10} \times 100 = 60^\circ\text{C}. Converting to absolute temperature gives T=60+273=333KT = 60 + 273 = 333\,\text{K}.

Step-by-Step Solution

1
Correct the measured resistance for zero error
True resistance Rθ=38Ω4Ω=34ΩR_\theta = 38\,\Omega - 4\,\Omega = 34\,\Omega
A positive zero error means the meter reads higher than the true value, so the zero error must be subtracted.
2
Calculate the temperature on the Celsius scale using linear interpolation
θ=RθR0R100R0×100C=34105010×100=2440×100=60C\theta = \frac{R_\theta - R_0}{R_{100} - R_0} \times 100^\circ\text{C} = \frac{34 - 10}{50 - 10} \times 100 = \frac{24}{40} \times 100 = 60^\circ\text{C}
The thermometric property varies linearly between the fixed points.
3
Convert the Celsius temperature to the thermodynamic (absolute) Kelvin scale
T=θ+273=60+273=333KT = \theta + 273 = 60 + 273 = 333\,\text{K}
The conversion from Celsius to Kelvin requires adding 273273 (or 273.15273.15).

Key Concept

Linear interpolation of thermometric properties with instrument zero error correction
Estimated Time:2m 0s
Question 71Question

A glass vessel with a linear expansivity of 9.0×106 K19.0 \times 10^{-6} \text{ K}^{-1} has a volume capacity of 300 cm3300 \text{ cm}^3 at 15C15^\circ\text{C}. It is completely filled with a liquid at this temperature. When the system is uniformly heated to 65C65^\circ\text{C}, a volume of 4.5 cm34.5 \text{ cm}^3 of the liquid overflows. What is the real cubic expansivity of the liquid?

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Answer: 3.27×104 K13.27 \times 10^{-4} \text{ K}^{-1}

Answer

The real cubic expansivity of the liquid is 3.27×104 K13.27 \times 10^{-4} \text{ K}^{-1}.
The real cubic expansivity of a liquid equals the sum of its apparent cubic expansivity and the cubical expansivity of the containing vessel. The apparent cubic expansivity is 4.5300×50=3.0×104 K1\frac{4.5}{300 \times 50} = 3.0 \times 10^{-4} \text{ K}^{-1}. The cubical expansivity of the vessel is 3×9.0×106=2.7×105 K13 \times 9.0 \times 10^{-6} = 2.7 \times 10^{-5} \text{ K}^{-1}. Summing these yields 3.27×104 K13.27 \times 10^{-4} \text{ K}^{-1}.

Step-by-Step Solution

1
Calculate the temperature change (ΔT\Delta T) and the apparent cubic expansivity (γa\gamma_a) of the liquid.
ΔT=65C15C=50 K\Delta T = 65^\circ\text{C} - 15^\circ\text{C} = 50 \text{ K}. γa=VoverflowV0ΔT=4.5300×50=3.0×104 K1\gamma_a = \frac{V_{\text{overflow}}}{V_0 \cdot \Delta T} = \frac{4.5}{300 \times 50} = 3.0 \times 10^{-4} \text{ K}^{-1}.
Apparent expansion measures the overflow relative to initial volume and temperature rise.
2
Calculate the cubical expansivity of the glass vessel (γv\gamma_v).
γv=3αv=3×(9.0×106 K1)=2.7×105 K1=0.27×104 K1\gamma_v = 3 \alpha_v = 3 \times (9.0 \times 10^{-6} \text{ K}^{-1}) = 2.7 \times 10^{-5} \text{ K}^{-1} = 0.27 \times 10^{-4} \text{ K}^{-1}.
The volume (cubical) expansivity of an isotropic solid container is three times its linear expansivity.
3
Determine the real cubic expansivity of the liquid (γr\gamma_r) using the relation γr=γa+γv\gamma_r = \gamma_a + \gamma_v.
γr=3.0×104 K1+0.27×104 K1=3.27×104 K1\gamma_r = 3.0 \times 10^{-4} \text{ K}^{-1} + 0.27 \times 10^{-4} \text{ K}^{-1} = 3.27 \times 10^{-4} \text{ K}^{-1}.
Real volume expansion equals the observed apparent expansion plus the expansion of the container.

Key Concept

Relationship between real expansivity, apparent expansivity, and vessel expansivity: γr=γa+γv\gamma_r = \gamma_a + \gamma_v, where γv=3α\gamma_v = 3\alpha.
Question 72Question

A liquid has a real cubic expansivity of 5.0×104 K15.0 \times 10^{-4} \text{ K}^{-1}. When this liquid is heated inside a metallic vessel, its apparent cubic expansivity is determined to be 4.1×104 K14.1 \times 10^{-4} \text{ K}^{-1}. What is the linear expansivity of the metallic vessel in 105 K110^{-5} \text{ K}^{-1}?

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Answer: 3

Answer

The linear expansivity of the metallic vessel is 3.0×105 K13.0 \times 10^{-5} \text{ K}^{-1}.
Real cubic expansivity of a liquid accounts for both the expansion of the liquid relative to the container and the expansion of the container itself: γr=γa+γv\gamma_r = \gamma_a + \gamma_v. Subtracting the apparent cubic expansivity (4.1×104 K14.1 \times 10^{-4} \text{ K}^{-1}) from the real cubic expansivity (5.0×104 K15.0 \times 10^{-4} \text{ K}^{-1}) gives the vessel's cubic expansivity of 0.9×104 K1=9.0×105 K10.9 \times 10^{-4} \text{ K}^{-1} = 9.0 \times 10^{-5} \text{ K}^{-1}. Dividing this value by 3 gives the vessel's linear expansivity: α=3.0×105 K1\alpha = 3.0 \times 10^{-5} \text{ K}^{-1}.

Step-by-Step Solution

1
Find the cubic expansivity of the vessel (γv\gamma_v)
γv=γrγa=5.0×1044.1×104=0.9×104 K1=9.0×105 K1\gamma_v = \gamma_r - \gamma_a = 5.0 \times 10^{-4} - 4.1 \times 10^{-4} = 0.9 \times 10^{-4} \text{ K}^{-1} = 9.0 \times 10^{-5} \text{ K}^{-1}
The real cubic expansivity of a liquid equals the sum of its apparent cubic expansivity and the cubic expansivity of the containing vessel (γr=γa+γv\gamma_r = \gamma_a + \gamma_v).
2
Calculate the linear expansivity of the vessel (α\alpha)
α=γv3=9.0×1053=3.0×105 K1\alpha = \frac{\gamma_v}{3} = \frac{9.0 \times 10^{-5}}{3} = 3.0 \times 10^{-5} \text{ K}^{-1}
For isotropic solids, volume (cubic) expansivity is three times the linear expansivity (γv=3α\gamma_v = 3\alpha).

Key Concept

Relationship between real cubic expansivity, apparent cubic expansivity, and vessel expansivity
Question 73Question

A liquid has a real cubic expansivity of 7.5×104 K17.5 \times 10^{-4}\text{ K}^{-1}. It is heated inside a metal vessel whose material has a linear expansivity of 2.0×105 K12.0 \times 10^{-5}\text{ K}^{-1}. What is the ratio of the real cubic expansivity of the liquid to its apparent cubic expansivity?

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Answer: 2523\frac{25}{23}

Answer

The ratio of the real cubic expansivity of the liquid to its apparent cubic expansivity is \(\frac{25}{23}\).
The real cubic expansivity of a liquid \(\gamma_r\) is related to its apparent cubic expansivity \(\gamma_a\) and the cubic expansivity of the container \(\gamma_v\) by the equation \(\gamma_r = \gamma_a + \gamma_v\). For a vessel made of material with linear expansivity \(\alpha\), \(\gamma_v = 3\alpha\). Substituting \(\alpha = 2.0 \times 10^{-5}\text{ K}^{-1}\) yields \(\gamma_v = 6.0 \times 10^{-5}\text{ K}^{-1} = 0.6 \times 10^{-4}\text{ K}^{-1}\). The apparent expansivity is \(\gamma_a = 7.5 \times 10^{-4} - 0.6 \times 10^{-4} = 6.9 \times 10^{-4}\text{ K}^{-1}\). The ratio \(\frac{\gamma_r}{\gamma_a}\) is therefore \(\frac{7.5 \times 10^{-4}}{6.9 \times 10^{-4}} = \frac{25}{23}\).

Step-by-Step Solution

1
Calculate the cubic expansivity of the metal vessel (\(\gamma_v\)) from its linear expansivity (\(\alpha\)).
\(\gamma_v = 3\alpha = 3 \times (2.0 \times 10^{-5}\text{ K}^{-1}) = 6.0 \times 10^{-5}\text{ K}^{-1} = 0.6 \times 10^{-4}\text{ K}^{-1}\)
The volume expansion coefficient of a solid vessel is three times its linear expansion coefficient.
2
Determine the apparent cubic expansivity (\(\gamma_a\)) using the relationship between real expansivity, apparent expansivity, and vessel expansivity.
\(\gamma_a = \gamma_r - \gamma_v = 7.5 \times 10^{-4}\text{ K}^{-1} - 0.6 \times 10^{-4}\text{ K}^{-1} = 6.9 \times 10^{-4}\text{ K}^{-1}\)
Real cubic expansivity of a liquid equals the sum of its apparent cubic expansivity and the cubic expansivity of the containing vessel.
3
Compute the ratio of real cubic expansivity to apparent cubic expansivity (\(\frac{\gamma_r}{\gamma_a}\)).
\(\frac{\gamma_r}{\gamma_a} = \frac{7.5 \times 10^{-4}}{6.9 \times 10^{-4}} = \frac{75}{69} = \frac{25}{23}\)
Dividing the given real cubic expansivity by the calculated apparent cubic expansivity gives the simplified fraction.

Key Concept

Thermal Expansion of Liquids: Relationship between Real and Apparent Expansivity
Estimated Time:1m 30s
Question 74Question

A metallic rod of initial length 2.0 m2.0\text{ m} experiences a temperature increase of 50 K50\text{ K}. If the linear expansivity of the metal is 1.5×105 K11.5 \times 10^{-5}\text{ K}^{-1}, what is the expansion in length of the rod in millimetres?

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Answer: 1.5

Answer

The expansion in length of the rod is 1.5 mm.
The expansion in length is calculated using ΔL=L0αΔT\Delta L = L_0 \alpha \Delta T. Substituting the values L0=2.0 mL_0 = 2.0\text{ m}, α=1.5×105 K1\alpha = 1.5 \times 10^{-5}\text{ K}^{-1}, and ΔT=50 K\Delta T = 50\text{ K} gives ΔL=1.5×103 m\Delta L = 1.5 \times 10^{-3}\text{ m}, which equals 1.5 mm1.5\text{ mm}.

Step-by-Step Solution

1
Identify known variables from the problem statement.
L0=2.0 mL_0 = 2.0\text{ m}, ΔT=50 K\Delta T = 50\text{ K}, and α=1.5×105 K1\alpha = 1.5 \times 10^{-5}\text{ K}^{-1}.
Listing given physical quantities clarifies which thermal expansion formula to apply.
2
Calculate the change in length in metres using ΔL=L0αΔT\Delta L = L_0 \alpha \Delta T.
ΔL=2.0 m×(1.5×105 K1)×50 K=0.0015 m\Delta L = 2.0\text{ m} \times (1.5 \times 10^{-5}\text{ K}^{-1}) \times 50\text{ K} = 0.0015\text{ m}.
Thermal expansion in one dimension is directly proportional to initial length, linear expansivity, and temperature change.
3
Convert the calculated expansion from metres to millimetres.
0.0015 m×1000 mm/m=1.5 mm0.0015\text{ m} \times 1000\text{ mm/m} = 1.5\text{ mm}.
The question explicitly requests the value in millimetres.

Key Concept

Linear thermal expansivity defines the fractional change in length per degree temperature change.
Question 75Question

A gas cylinder fitted with a pressure relief valve contains a fixed mass of an ideal gas at an initial absolute pressure of 2.50×105 Pa2.50 \times 10^5\text{ Pa} and a temperature of 27C27^\circ\text{C}. The valve is designed to open when the internal gauge pressure exceeds 3.20×105 Pa3.20 \times 10^5\text{ Pa}. Assuming the atmospheric pressure is 1.00×105 Pa1.00 \times 10^5\text{ Pa}, at what temperature will the relief valve open?

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Answer: 231C231^\circ\text{C}

Answer

231C231^\circ\text{C}
The correct answer is 231C231^\circ\text{C}. To solve this, first convert the initial temperature to Kelvin: T1=27+273=300 KT_1 = 27 + 273 = 300\text{ K}. Next, calculate the final absolute pressure by adding the atmospheric pressure to the given gauge pressure: P2=3.20×105 Pa+1.00×105 Pa=4.20×105 PaP_2 = 3.20 \times 10^5\text{ Pa} + 1.00 \times 10^5\text{ Pa} = 4.20 \times 10^5\text{ Pa}. Applying Gay-Lussac's Law (P1T1=P2T2\frac{P_1}{T_1} = \frac{P_2}{T_2}) gives T2=300×4.20×1052.50×105=504 KT_2 = 300 \times \frac{4.20 \times 10^5}{2.50 \times 10^5} = 504\text{ K}. Converting back to Celsius gives 504273=231C504 - 273 = 231^\circ\text{C}.

Step-by-Step Solution

1
Convert the initial temperature from Celsius to Kelvin and determine the initial absolute pressure.
T1=27+273=300 KT_1 = 27 + 273 = 300\text{ K}, P1=2.50×105 PaP_1 = 2.50 \times 10^5\text{ Pa}.
Gas laws require thermodynamic (absolute) temperature in Kelvin.
2
Calculate the final total absolute pressure (P2P_2) at which the valve opens.
P2=Pgauge+Patm=3.20×105 Pa+1.00×105 Pa=4.20×105 PaP_2 = P_{\text{gauge}} + P_{\text{atm}} = 3.20 \times 10^5\text{ Pa} + 1.00 \times 10^5\text{ Pa} = 4.20 \times 10^5\text{ Pa}.
Gauge pressure measures the pressure difference relative to atmospheric pressure; gas laws use absolute pressure.
3
Apply Gay-Lussac's (Pressure) Law at constant volume to find the final Kelvin temperature (T2T_2).
P1T1=P2T2    T2=300×4.20×1052.50×105=504 K\frac{P_1}{T_1} = \frac{P_2}{T_2} \implies T_2 = 300 \times \frac{4.20 \times 10^5}{2.50 \times 10^5} = 504\text{ K}.
For a fixed volume of ideal gas, absolute pressure is directly proportional to absolute temperature.
4
Convert the final temperature back to degrees Celsius.
t2=504273=231Ct_2 = 504 - 273 = 231^\circ\text{C}.
The question asks for the temperature in degrees Celsius.

Key Concept

Pressure Law (Gay-Lussac's Law) and Absolute vs Gauge Pressure
Estimated Time:2m 0s
Question 76Question

A liquid has a density of 840 kg m3840\text{ kg m}^{-3} at 10C10^\circ\text{C}. It is heated inside a container whose material has a linear expansivity of 2.0×105 K12.0 \times 10^{-5}\text{ K}^{-1}. If the measured apparent cubic expansivity of the liquid in this container is 4.4×104 K14.4 \times 10^{-4}\text{ K}^{-1}, what is the density of the liquid at 110C110^\circ\text{C} in kg m3\text{kg m}^{-3}?

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Answer: 800

Answer

800 kg m^-3
To find the density of the liquid at the elevated temperature, we must use its real cubic expansivity γr\gamma_r. The vessel expands with a cubic expansivity of γv=3α=6.0×105 K1\gamma_v = 3\alpha = 6.0 \times 10^{-5}\text{ K}^{-1}. The real cubic expansivity of the liquid is γr=γa+γv=4.4×104+0.6×104=5.0×104 K1\gamma_r = \gamma_a + \gamma_v = 4.4 \times 10^{-4} + 0.6 \times 10^{-4} = 5.0 \times 10^{-4}\text{ K}^{-1}. Using the density variation formula ρ2=ρ11+γrΔT\rho_2 = \frac{\rho_1}{1 + \gamma_r \Delta T}, we evaluate 8401+(5.0×104×100)=8401.05=800 kg m3\frac{840}{1 + (5.0 \times 10^{-4} \times 100)} = \frac{840}{1.05} = 800\text{ kg m}^{-3}.

Step-by-Step Solution

1
Calculate the cubic expansivity of the container material
γv=6.0×105 K1\gamma_v = 6.0 \times 10^{-5}\text{ K}^{-1}
The volume (cubic) expansivity of a solid container is three times its linear expansivity (γv=3α\gamma_v = 3\alpha).
2
Determine the real cubic expansivity of the liquid
γr=5.0×104 K1\gamma_r = 5.0 \times 10^{-4}\text{ K}^{-1}
The real cubic expansivity is the sum of the apparent cubic expansivity and the cubic expansivity of the container (γr=γa+γv\gamma_r = \gamma_a + \gamma_v).
3
Determine the change in temperature
ΔT=100 K\Delta T = 100\text{ K}
Subtract the initial temperature from the final temperature: 110C10C=100 K110^\circ\text{C} - 10^\circ\text{C} = 100\text{ K}.
4
Calculate the final density of the liquid at 110C110^\circ\text{C}
ρ2=800 kg m3\rho_2 = 800\text{ kg m}^{-3}
Density varies inversely with volumetric expansion according to ρ2=ρ11+γrΔT\rho_2 = \frac{\rho_1}{1 + \gamma_r \Delta T}.

Key Concept

Relationship between real expansivity, apparent expansivity, container expansion, and density change in fluids
Question 77Question

A steel rod and a brass rod are arranged such that the difference between their lengths remains constant at 10 cm10\text{ cm} at all temperatures. If the linear expansivity of steel is 1.2×105 K11.2 \times 10^{-5}\text{ K}^{-1} and that of brass is 1.8×105 K11.8 \times 10^{-5}\text{ K}^{-1}, what is the initial length of the steel rod in centimetres?

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Answer: 30

Answer

The initial length of the steel rod is 30 cm30\text{ cm}.
For the length difference between two rods to remain constant regardless of temperature change, both rods must undergo equal absolute expansion (\(\Delta L_1 = \Delta L_2\)). Since \(\Delta L = L_0 \alpha \Delta T\), this requires \(L_1 \alpha_1 = L_2 \alpha_2\). Substituting \(L_{\text{brass}} = L_{\text{steel}} - 10\text{ cm}\) and the given expansivity values gives \(1.2 \times 10^{-5} L_{\text{steel}} = 1.8 \times 10^{-5} (L_{\text{steel}} - 10)\), which simplifies to \(0.6 L_{\text{steel}} = 18\), giving \(L_{\text{steel}} = 30\text{ cm}\).

Step-by-Step Solution

1
Relate the condition for a constant difference in length to individual expansions
\(\Delta L_{\text{steel}} = \Delta L_{\text{brass}}\)
If the difference between the two lengths is constant across temperature changes, both rods must increase in length by the exact same amount for any given temperature change.
2
Apply the linear thermal expansion formula to both rods
\(L_{\text{steel}} \alpha_{\text{steel}} = L_{\text{brass}} \alpha_{\text{brass}}\)
Since \(\Delta L = L_0 \alpha \Delta T\), setting \(\Delta L_{\text{steel}} = \Delta L_{\text{brass}}\) gives \(L_{\text{steel}} \alpha_{\text{steel}} \Delta T = L_{\text{brass}} \alpha_{\text{brass}} \Delta T\). Cancelling \(\Delta T\) yields \(L_{\text{steel}} \alpha_{\text{steel}} = L_{\text{brass}} \alpha_{\text{brass}}\).
3
Substitute the length relationship into the equation
\(L_{\text{steel}} (1.2 \times 10^{-5}) = (L_{\text{steel}} - 10) (1.8 \times 10^{-5})\)
Because brass has a larger linear expansivity than steel, the brass rod must be shorter than the steel rod so that their products of length and expansivity remain equal, hence \(L_{\text{brass}} = L_{\text{steel}} - 10\text{ cm}\).
4
Solve for the length of the steel rod
\(L_{\text{steel}} = 30\text{ cm}\)
Dividing both sides by \(10^{-5}\) gives \(1.2 L_{\text{steel}} = 1.8 L_{\text{steel}} - 18\). Rearranging gives \(0.6 L_{\text{steel}} = 18\), which yields \(L_{\text{steel}} = \frac{18}{0.6} = 30\text{ cm}\).

Key Concept

Equal absolute linear expansion for constant length difference
Estimated Time:2m 0s
Question 78Question

A pneumatic cylinder in a hydraulic brake mechanism contains 0.050 m30.050\text{ m}^3 of an ideal gas at an initial pressure of 1.20×105 Pa1.20 \times 10^5\text{ Pa} and a temperature of 27C27^\circ\text{C}. The gas is first compressed isothermally to a volume of 0.020 m30.020\text{ m}^3, and then heated at constant volume until its pressure reaches 6.00×105 Pa6.00 \times 10^5\text{ Pa}. What is the final temperature of the gas in degrees Celsius?

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Answer: 327C327^\circ\text{C}

Answer

The final temperature of the gas is 327C327^\circ\text{C}.
First, converting the initial temperature gives T1=27C+273=300 KT_1 = 27^\circ\text{C} + 273 = 300\text{ K}. For the isothermal compression, the pressure increases to P2=P1×V1V2=1.20×105×0.0500.020=3.00×105 PaP_2 = P_1 \times \frac{V_1}{V_2} = 1.20 \times 10^5 \times \frac{0.050}{0.020} = 3.00 \times 10^5\text{ Pa}. Next, during the constant volume heating step to P3=6.00×105 PaP_3 = 6.00 \times 10^5\text{ Pa}, the pressure doubles, requiring the absolute temperature to double from 300 K300\text{ K} to 600 K600\text{ K}. Converting 600 K600\text{ K} back to Celsius yields 600273=327C600 - 273 = 327^\circ\text{C}.

Step-by-Step Solution

1
Convert the initial temperature from Celsius to Kelvin.
T1=27+273=300 KT_1 = 27 + 273 = 300\text{ K}.
Gas laws strictly require thermodynamic temperatures expressed in Kelvin.
2
Apply Boyle's Law (P1V1=P2V2P_1 V_1 = P_2 V_2) to determine the intermediate pressure P2P_2 after isothermal compression at constant temperature T2=300 KT_2 = 300\text{ K}.
P2=P1V1V2=(1.20×105 Pa)(0.050 m3)0.020 m3=3.00×105 PaP_2 = \frac{P_1 V_1}{V_2} = \frac{(1.20 \times 10^5\text{ Pa})(0.050\text{ m}^3)}{0.020\text{ m}^3} = 3.00 \times 10^5\text{ Pa}.
During an isothermal process, the product of pressure and volume remains constant.
3
Apply Pressure Law (Gay-Lussac's Law) for the second stage, where volume remains constant (V3=V2=0.020 m3V_3 = V_2 = 0.020\text{ m}^3) while pressure increases from P2=3.00×105 PaP_2 = 3.00 \times 10^5\text{ Pa} to P3=6.00×105 PaP_3 = 6.00 \times 10^5\text{ Pa}.
P2T2=P3T3    T3=T2×P3P2=300 K×6.00×105 Pa3.00×105 Pa=600 K\frac{P_2}{T_2} = \frac{P_3}{T_3} \implies T_3 = T_2 \times \frac{P_3}{P_2} = 300\text{ K} \times \frac{6.00 \times 10^5\text{ Pa}}{3.00 \times 10^5\text{ Pa}} = 600\text{ K}.
At constant volume, pressure is directly proportional to absolute temperature.
4
Convert the final temperature T3T_3 back to degrees Celsius.
t3=600273=327Ct_3 = 600 - 273 = 327^\circ\text{C}.
The question explicitly requests the final temperature in degrees Celsius.

Key Concept

Multi-stage gas processes combining Boyle's Law and Pressure Law using the Ideal Gas Equation
Question 79Question

Match each kinetic theory parameter of an ideal gas on the left with its corresponding microscopic physical description on the right.

Click a left item, then click its matching right item

Items

Temperature of a gas
Gas pressure on container walls
Root-mean-square (r.m.s.) speed of gas molecules

Matches

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Answer

Temperature corresponds to the measure of average translational kinetic energy; Gas pressure corresponds to the rate of momentum transfer per unit area from wall collisions; Root-mean-square speed corresponds to the square root of the mean of squared speeds.
Temperature is directly linked to the average kinetic energy of molecules, gas pressure arises from wall collisions delivering impulse per unit area, and r.m.s. speed is the square root of mean square velocity.

Step-by-Step Solution

1
Identify the microscopic origin of temperature.
Temperature represents the average translational kinetic energy of gas molecules.
From the kinetic theory equation 12mv2=32kBT\frac{1}{2}m\overline{v^2} = \frac{3}{2}k_B T, absolute temperature directly measures molecular kinetic energy.
2
Identify the microscopic origin of pressure.
Pressure is caused by molecular collisions with container walls.
Each collision transfers momentum to the wall; force is the time rate of momentum change, and force per unit area defines pressure.
3
Identify the definition of root-mean-square speed.
r.m.s. speed is the square root of the average of squared molecular speeds.
It accounts for the statistical distribution of molecular velocities in a gas sample.

Key Concept

Microscopic interpretation of macroscopic gas properties via Kinetic Theory of Matter
Question 80Question

A thin flat metal plate has an initial surface area of 0.5 m20.5\text{ m}^2 at 10C10^\circ\text{C}. When the plate is heated to a final temperature of 110C110^\circ\text{C}, its surface area increases by 1.8×103 m21.8 \times 10^{-3}\text{ m}^2. What is the coefficient of cubical expansivity of the metal?

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Answer: 5.4×105 K15.4 \times 10^{-5}\text{ K}^{-1}

Answer

5.4×105 K15.4 \times 10^{-5}\text{ K}^{-1}
The correct answer is derived by first finding the area expansivity β=ΔAA0ΔT=3.6×105 K1\beta = \frac{\Delta A}{A_0 \Delta T} = 3.6 \times 10^{-5}\text{ K}^{-1}. Since β=2α\beta = 2\alpha, the linear expansivity α=1.8×105 K1\alpha = 1.8 \times 10^{-5}\text{ K}^{-1}. The cubical expansivity is γ=3α=5.4×105 K1\gamma = 3\alpha = 5.4 \times 10^{-5}\text{ K}^{-1}.

Step-by-Step Solution

1
Calculate the temperature change ΔT\Delta T
ΔT=110C10C=100 K\Delta T = 110^\circ\text{C} - 10^\circ\text{C} = 100\text{ K}
Expansion calculations depend on the temperature increase.
2
Determine the coefficient of area expansivity β\beta
β=ΔAA0ΔT=1.8×1030.5×100=3.6×105 K1\beta = \frac{\Delta A}{A_0 \Delta T} = \frac{1.8 \times 10^{-3}}{0.5 \times 100} = 3.6 \times 10^{-5}\text{ K}^{-1}
The area expansion formula is ΔA=A0βΔT\Delta A = A_0 \beta \Delta T.
3
Calculate the coefficient of linear expansivity α\alpha
α=β2=3.6×1052=1.8×105 K1\alpha = \frac{\beta}{2} = \frac{3.6 \times 10^{-5}}{2} = 1.8 \times 10^{-5}\text{ K}^{-1}
Area expansivity is twice the linear expansivity (β=2α\beta = 2\alpha).
4
Calculate the coefficient of cubical expansivity γ\gamma
γ=3α=3×(1.8×105)=5.4×105 K1\gamma = 3\alpha = 3 \times (1.8 \times 10^{-5}) = 5.4 \times 10^{-5}\text{ K}^{-1}
Cubical expansivity is three times the linear expansivity (γ=3α\gamma = 3\alpha).

Key Concept

Relationship between linear (α\alpha), area (β\beta), and volume (γ\gamma) expansivities: β=2α\beta = 2\alpha and γ=3α\gamma = 3\alpha.
Estimated Time:1m 30s
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