To investigate how reactant surface area affects the rate of a chemical reaction, students performed three trials. In each trial, of calcium carbonate () was added to of hydrochloric acid () at an initial temperature of in an uninsulated beaker. The reaction is represented by the following equation:
The students recorded the particle size of the , the time required for the reaction to go to completion, and the maximum temperature reached during each trial. The results are shown in the table below:
| Trial | Particle Size | Time to Completion (s) | Maximum Temperature Reached () |
|---|---|---|---|
| Large chunks | |||
| Small chips | |||
| Fine powder |
Which of the following statements best explains how the maximum temperature reached acts as a confounding variable that prevents the students from drawing a valid conclusion about the effect of particle size on the reaction rate?
- AThe maximum temperature reached is the independent variable, which the students should have controlled by varying the initial mass of the calcium carbonate added to each beaker.
- BThe temperature differences indicate that Trial 1 was conducted in a colder room than Trial 3, showing a failure to keep the ambient experimental environment constant.
- The unequal temperature rise among the trials increases the average kinetic energy of the reactants in the faster trials, meaning the difference in reaction times cannot be attributed solely to the difference in particle size.Cevap
- DThe maximum temperature is a controlled variable because the reactants in all three trials began at the same initial temperature of 20.0°C.
Cevap
The correct answer explains that the unequal temperature rise among the trials increases the average kinetic energy of the reactants in the faster trials, meaning the difference in reaction times cannot be attributed solely to the difference in particle size.
The correct answer explains that the unequal temperature rise among the trials increases the average kinetic energy of the reactants in the faster trials, meaning the difference in reaction times cannot be attributed solely to the difference in particle size. Since temperature is known to affect reaction rate, the fact that the temperature rose much higher in the fine powder trial than in the large chunks trial means that both temperature and surface area changed simultaneously, confounding the results.
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A confounding variable is an uncontrolled factor that varies systematically with the independent variable, making it impossible to isolate the true cause of the observed changes in the dependent variable.
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