Unlike modern Portland cement, which degrades structurally when exposed to saltwater due to calcium silicate hydrate leaching, ancient Roman marine concrete (opus caementicium) increased in compressive strength over centuries submerged in seawater. Recent microstructural analyses indicate that this resilience stems from a continuous post-curing reaction between seawater and volcanic ash pozzolans, primarily pumice containing the mineral phillipsite. When alkaline seawater percolates through interlocking micropores in the lime-ash mortar, it dissolves residual volcanic glass, triggering the precipitation of interlocking crystalline plates of aluminous tobermorite and phillipsite within existing voids. These authigenic minerals not only arrest propagation of microcracks generated by mechanical wave action but also reinforce the surrounding matrix. However, because this crystallization relies on the dissolution of permeable, unconsolidated ash components, synthetic formulations that fully vitrify the ash prior to mixing fail to exhibit any comparable self-strengthening behavior.
Which of the following is most strongly supported by the passage regarding the structural properties of Roman marine concrete?
- AThe infiltration of seawater would cause ancient Roman concrete to deteriorate if the submerged structure were completely shielded from mechanical wave action.
- BModern Portland cement could achieve long-term resilience comparable to Roman concrete if mixed with high concentrations of industrial silica fume.
- The formation of crystalline plates that prevent crack propagation requires that the volcanic ash in the original mixture retain non-vitrified, dissolvable constituents.Cevap
- DMicroscopic fractures within the concrete mortar must already be present before any dissolution of residual volcanic glass by seawater can occur.
- EThe compressive strength of Roman marine concrete submerged in seawater increases at a constant, uniform rate indefinitely.