Question

Difficulty: MediumStates of Matter and Phase Changes

During an air conditioning service, an automotive technician uses a recovery machine to extract refrigerant. The machine pulls hot, high-pressure refrigerant vapor from the vehicle and continuously removes heat from it until it becomes a subcooled liquid in a storage cylinder. Arrange the following thermodynamic events in the chronological order they occur during this continuous cooling process.

  1. 1The superheated vapor cools down steadily, decreasing its molecular kinetic energy.
  2. 2The vapor reaches its specific saturation temperature for the pressure inside the cylinder.
  3. 3The temperature remains completely constant as latent heat of condensation is released.
  4. 4The last remaining vapor transforms into liquid, ending the phase change plateau.
  5. 5The completely liquid refrigerant drops in temperature as sensible heat is further removed.

Answer

The sequence follows a continuous cooling curve: initial sensible cooling of the vapor, reaching the saturation point, the constant-temperature condensation plateau, the end of the phase change, and finally the sensible cooling of the resulting liquid.
As heat is continuously removed from a superheated vapor, its temperature first drops due to sensible heat loss until it reaches the saturation temperature (condensation point). During the actual phase change from gas to liquid, the temperature remains entirely constant as latent heat is released. Once condensation is 100% complete, the temperature of the newly formed liquid begins to drop again.

Step-by-Step Solution

1
Identify the initial state and process described in the scenario.
The substance starts as a hot, superheated vapor and is continuously losing thermal energy.
Establishing the starting point is necessary to track the thermal sequence accurately.
2
Determine the first phase of cooling prior to condensation.
The vapor cools down steadily, lowering its molecular kinetic energy until it hits the saturation temperature.
A gas must lose sensible heat and cool to its exact condensation point before it can change state.
3
Analyze the phase change behavior.
The temperature stalls and remains completely constant while the vapor condenses into liquid.
During a phase change, heat removal changes the physical state of the matter (releasing latent heat) without changing the temperature.
4
Determine the final phase of cooling after condensation is complete.
Once the last bit of vapor transforms into liquid, the liquid's temperature begins to drop as sensible heat is removed.
After the phase change plateau ends, further heat removal resumes lowering the temperature of the substance.

Key Concept

States of Matter and Phase Changes
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