Question

Difficulty: MediumVapour Pressure, Boiling, Evaporation, and Relative Humidity

On a warm afternoon, the air temperature in a physics laboratory is 30C30^\circ\text{C}, where the saturated vapour pressure of water is 32.0 mmHg32.0\text{ mmHg}. When the air is cooled, condensation just begins to form on a metal vessel at 20C20^\circ\text{C}. Given that the saturated vapour pressure of water at 20C20^\circ\text{C} is 17.6 mmHg17.6\text{ mmHg}, what is the relative humidity of the air in percentage?

Answer: 55 %

Answer

The relative humidity of the air is 55%55\%.
The dew point is the temperature at which condensation begins, indicating that the actual water vapour pressure present in the air equals the saturated vapour pressure at 20C20^\circ\text{C}, which is 17.6 mmHg17.6\text{ mmHg}. Dividing this actual vapour pressure by the saturated vapour pressure at the ambient air temperature of 30C30^\circ\text{C} (32.0 mmHg32.0\text{ mmHg}) and multiplying by 100%100\% yields 17.632.0×100%=55%\frac{17.6}{32.0} \times 100\% = 55\%.

Step-by-Step Solution

1
Determine the actual vapour pressure in the air
Actual vapour pressure = 17.6 mmHg17.6\text{ mmHg}
Condensation starts at the dew point (20C20^\circ\text{C}), meaning the actual vapour pressure in the air equals the saturated vapour pressure at the dew point.
2
Determine the saturated vapour pressure at the air temperature
Saturated vapour pressure at 30C30^\circ\text{C} = 32.0 mmHg32.0\text{ mmHg}
This is the maximum vapour pressure the air can exert at its current ambient temperature.
3
Compute the relative humidity percentage
Relative Humidity=17.632.0×100%=55%\text{Relative Humidity} = \frac{17.6}{32.0} \times 100\% = 55\%
Relative humidity is defined as the ratio of actual vapour pressure to saturated vapour pressure at air temperature, expressed as a percentage.

Key Concept

Calculation of relative humidity from saturated vapour pressure at dew point and air temperature
Estimated Time:1m 30s
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