Question

Difficulty: MediumVapour Pressure, Boiling, Evaporation, and Relative Humidity

At a weather recording station, the air temperature is 25C25^\circ\text{C} and the relative humidity is recorded as 60%60\%. If the saturated vapour pressure of water at 25C25^\circ\text{C} is 24.0 mmHg24.0\text{ mmHg}, what is the actual partial vapour pressure of water present in the atmosphere?

  1. 14.4 mmHg14.4\text{ mmHg}Answer
  2. B
    40.0 mmHg40.0\text{ mmHg}
  3. C
    9.6 mmHg9.6\text{ mmHg}
  4. D
    24.0 mmHg24.0\text{ mmHg}

Answer

The actual partial vapour pressure of water present in the atmosphere is 14.4 mmHg14.4\text{ mmHg}.
Relative humidity is defined as the ratio of actual partial vapour pressure to saturated vapour pressure at the same temperature, expressed as a percentage. Therefore, the actual partial vapour pressure is 60%60\% of 24.0 mmHg24.0\text{ mmHg}, which equals 14.4 mmHg14.4\text{ mmHg}.

Step-by-Step Solution

1
State the standard relationship defining relative humidity in terms of vapour pressures.
Relative Humidity (R.H.)=Partial Vapour PressureSaturated Vapour Pressure at Air Temp×100%\text{Relative Humidity (R.H.)} = \frac{\text{Partial Vapour Pressure}}{\text{Saturated Vapour Pressure at Air Temp}} \times 100\%
Relative humidity quantifies how close the air is to maximum moisture saturation at a given temperature.
2
Substitute the given numerical values into the relative humidity formula.
60%=P24.0 mmHg×100%60\% = \frac{P}{24.0\text{ mmHg}} \times 100\%
Here PP represents the unknown actual partial vapour pressure of water in the atmosphere.
3
Rearrange the equation to isolate and solve for PP.
P=0.60×24.0 mmHg=14.4 mmHgP = 0.60 \times 24.0\text{ mmHg} = 14.4\text{ mmHg}
Multiplying the saturated vapour pressure by 0.600.60 yields the actual partial vapour pressure.

Key Concept

Relative Humidity and Vapour Pressure Calculation
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