Question

Difficulty: MediumThe Mole Concept, Avogadro's Constant, and Molar Mass

What is the total number of nitrogen atoms contained in a 5.60 dm35.60\text{ dm}^3 sample of dinitrogen monoxide gas (N2O\text{N}_2\text{O}) measured at standard temperature and pressure (STP\text{STP})? [NA=6.02×1023 mol1; Molar volume of gas at STP =22.4 dm3mol1][N_A = 6.02 \times 10^{23}\text{ mol}^{-1}\text{; Molar volume of gas at STP } = 22.4\text{ dm}^3\text{mol}^{-1}]

  1. 3.01×10233.01 \times 10^{23}Answer
  2. B
    2.81×10232.81 \times 10^{23}
  3. C
    1.51×10231.51 \times 10^{23}
  4. D
    4.52×10234.52 \times 10^{23}

Answer

3.01×10233.01 \times 10^{23} nitrogen atoms
The correct answer of 3.01×10233.01 \times 10^{23} is calculated by determining the amount in moles of dinitrogen monoxide gas (5.60 dm3/22.4 dm3mol1=0.25 mol5.60\text{ dm}^3 / 22.4\text{ dm}^3\text{mol}^{-1} = 0.25\text{ mol}), multiplying by 2 because there are two nitrogen atoms per N2O\text{N}_2\text{O} molecule (0.50 mol0.50\text{ mol} of N atoms), and multiplying by Avogadro's constant (0.50×6.02×1023=3.01×10230.50 \times 6.02 \times 10^{23} = 3.01 \times 10^{23}).

Step-by-Step Solution

1
Calculate the moles of dinitrogen monoxide gas at STP
Moles of N2O=5.60 dm322.4 dm3mol1=0.25 mol\text{Moles of N}_2\text{O} = \frac{5.60\text{ dm}^3}{22.4\text{ dm}^3\text{mol}^{-1}} = 0.25\text{ mol}
At STP, one mole of any ideal gas occupies a molar volume of 22.4 dm³.
2
Determine the number of moles of nitrogen atoms
Moles of N atoms=0.25 mol×2=0.50 mol\text{Moles of N atoms} = 0.25\text{ mol} \times 2 = 0.50\text{ mol}
Each formula unit of dinitrogen monoxide (N₂O) contains 2 atoms of nitrogen.
3
Convert moles of nitrogen atoms to the total number of atoms using Avogadro's constant
Number of N atoms=0.50 mol×6.02×1023 atoms/mol=3.01×1023 atoms\text{Number of N atoms} = 0.50\text{ mol} \times 6.02 \times 10^{23}\text{ atoms/mol} = 3.01 \times 10^{23}\text{ atoms}
Avogadro's constant provides the number of particles per mole of substance.

Key Concept

Mole Concept and Avogadro's Constant applied to Gas Molar Volume
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