Question

Difficulty: MediumLatent Heat and Changes of State

An electric heater rated at 200 W200\text{ W} is used to heat a 0.40 kg0.40\text{ kg} sample of a pure solid substance maintained at its melting point. If it takes 2 minutes2\text{ minutes} for exactly half of the sample to melt into liquid at the same temperature, what is the specific latent heat of fusion of the substance?

  1. 1.2×105 J kg11.2 \times 10^5\text{ J kg}^{-1}Answer
  2. B
    6.0×104 J kg16.0 \times 10^4\text{ J kg}^{-1}
  3. C
    2.0×103 J kg12.0 \times 10^3\text{ J kg}^{-1}
  4. D
    1.2×107 J kg11.2 \times 10^7\text{ J kg}^{-1}

Answer

The specific latent heat of fusion of the substance is 1.2×105 J kg11.2 \times 10^5\text{ J kg}^{-1}.
The thermal energy absorbed during melting is Q=P×t=200 W×120 s=24,000 JQ = P \times t = 200\text{ W} \times 120\text{ s} = 24,000\text{ J}. Since only half of the 0.40 kg0.40\text{ kg} sample melts, the mass undergoing phase change is 0.20 kg0.20\text{ kg}. Dividing the heat absorbed (24,000 J24,000\text{ J}) by the melted mass (0.20 kg0.20\text{ kg}) yields the correct specific latent heat of fusion of 1.2×105 J kg11.2 \times 10^5\text{ J kg}^{-1}.

Step-by-Step Solution

1
Calculate total thermal energy supplied by the heater.
Q=P×t=200 W×(2×60 s)=24,000 JQ = P \times t = 200\text{ W} \times (2 \times 60\text{ s}) = 24,000\text{ J}
Electrical energy supplied is converted completely into thermal energy.
2
Determine the mass of substance that melted.
mmelted=12×0.40 kg=0.20 kgm_{\text{melted}} = \frac{1}{2} \times 0.40\text{ kg} = 0.20\text{ kg}
Only half of the total mass undergoes phase change.
3
Compute the specific latent heat of fusion LfL_f.
Lf=Qmmelted=24,000 J0.20 kg=120,000 J kg1=1.2×105 J kg1L_f = \frac{Q}{m_{\text{melted}}} = \frac{24,000\text{ J}}{0.20\text{ kg}} = 120,000\text{ J kg}^{-1} = 1.2 \times 10^5\text{ J kg}^{-1}
Phase change occurs at constant temperature using the latent heat equation Q=mLfQ = m L_f.

Key Concept

Latent Heat of Fusion and Energy Balance
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