Question

Difficulty: MediumPhysical and Chemical Properties of Acids and Bases

Match each chemical reaction involving acids or bases listed on the left with its correct characteristic observation or product on the right.

  • Reaction of dilute HClHCl with Na2CO3Na_2CO_3Effervescence of a gas (CO2CO_2) that turns lime water milky
  • Heating NH4ClNH_4Cl with aqueous NaOHNaOHEvolution of a pungent gas (NH3NH_3) that turns moist red litmus paper blue
  • Reaction of dilute H2SO4H_2SO_4 with zinc metalLiberation of a colorless gas (H2H_2) that burns with a pop sound
  • Reaction of aqueous NaOHNaOH with dilute HNO3HNO_3Neutralization reaction forming a salt and water without gas evolution

Answer

Reaction of dilute HClHCl with Na2CO3Na_2CO_3 pairs with effervescence of carbon(IV) oxide gas; heating NH4ClNH_4Cl with aqueous NaOHNaOH pairs with evolution of pungent ammonia gas; reaction of dilute H2SO4H_2SO_4 with zinc metal pairs with liberation of hydrogen gas; and reaction of aqueous NaOHNaOH with dilute HNO3HNO_3 pairs with neutralization forming a salt and water without gas evolution.
Each acid and base chemical property produces a distinct, diagnostic observation: acid + carbonate yields carbon(IV) oxide (CO2CO_2), base + ammonium salt yields ammonia (NH3NH_3), acid + reactive metal yields hydrogen (H2H_2), and acid + base (hydroxide) results in neutralisation forming salt and water.

Step-by-Step Solution

1
Analyze acid-trioxocarbonate(IV) reaction property.
2HCl(aq)+Na2CO3(aq)2NaCl(aq)+H2O(l)+CO2(g)2HCl_{(aq)} + Na_2CO_{3(aq)} \rightarrow 2NaCl_{(aq)} + H_2O_{(l)} + CO_{2(g)}. The evolved CO2CO_2 gas causes effervescence and turns lime water milky.
Acids liberate carbon(IV) oxide gas from trioxocarbonates(IV).
2
Analyze base-ammonium salt reaction property.
NH4Cl(s)+NaOH(aq)NaCl(aq)+H2O(l)+NH3(g)NH_4Cl_{(s)} + NaOH_{(aq)} \rightarrow NaCl_{(aq)} + H_2O_{(l)} + NH_{3(g)}. Ammonia gas is pungent and alkaline, turning moist red litmus paper blue.
Soluble bases displace ammonia from ammonium salts when heated.
3
Analyze acid-metal displacement reaction property.
Zn(s)+H2SO4(aq)ZnSO4(aq)+H2(g)Zn_{(s)} + H_2SO_{4(aq)} \rightarrow ZnSO_{4(aq)} + H_{2(g)}. Hydrogen gas burns with a pop sound.
Dilute acids react with metals above hydrogen in the electrochemical series to yield hydrogen gas.
4
Analyze acid-base neutralization property.
NaOH(aq)+HNO3(aq)NaNO3(aq)+H2O(l)NaOH_{(aq)} + HNO_{3(aq)} \rightarrow NaNO_{3(aq)} + H_2O_{(l)}. This is a neutralisation reaction yielding salt and water.
Soluble metal hydroxides react with acids to form salt and water only.

Key Concept

Chemical properties of acids and bases including gas evolution tests and neutralization
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