Question

Difficulty: EasyIron: Blast Furnace Extraction, Rusting Prevention, and Chemical Compounds

During the industrial extraction of iron in the blast furnace, limestone (CaCO3\text{CaCO}_3) is decomposed by heat to form calcium oxide (CaO\text{CaO}), which then reacts with silica (SiO2\text{SiO}_2) impurities present in the ore. Which of the following chemical formulas represents the molten slag produced from this reaction?

  1. CaSiO3\text{CaSiO}_3Answer
  2. B
    FeSiO3\text{FeSiO}_3
  3. C
    CaCO3\text{CaCO}_3
  4. D
    CaO\text{CaO}

Answer

CaSiO3\text{CaSiO}_3 (Calcium trioxosilicate(IV))
In the lower region of the blast furnace, limestone (CaCO3\text{CaCO}_3) decomposes into calcium oxide (CaO\text{CaO}). The basic CaO\text{CaO} reacts with acidic silica (SiO2\text{SiO}_2) impurities present in hematite to form molten calcium trioxosilicate(IV) (CaSiO3\text{CaSiO}_3), commonly known as slag.

Step-by-Step Solution

1
Identify thermal decomposition of limestone
CaCO3(s)CaO(s)+CO2(g)\text{CaCO}_3(s) \rightarrow \text{CaO}(s) + \text{CO}_2(g)
High temperatures in the blast furnace break down limestone into basic calcium oxide.
2
Combine basic oxide flux with acidic silica impurity
CaO(s)+SiO2(s)CaSiO3(l)\text{CaO}(s) + \text{SiO}_2(s) \rightarrow \text{CaSiO}_3(l)
Calcium oxide acts as a basic flux that neutralizes acidic sand/silica impurities to form molten slag.

Key Concept

Slag Formation in Iron Extraction
Estimated Time:45s
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