Question

Difficulty: EasyIron: Blast Furnace Extraction, Rusting Prevention, and Chemical Compounds

During the industrial extraction of iron in a blast furnace, hematite (Fe2O3Fe_2O_3) is reduced to iron in the upper region of the furnace. Which chemical species acts as the primary reducing agent in this upper zone?

  1. Carbon(II) oxide (COCO)Answer
  2. B
    Solid carbon (CC)
  3. C
    Calcium oxide (CaOCaO)
  4. D
    Carbon(IV) oxide (CO2CO_2)

Answer

Carbon(II) oxide (COCO)
In the blast furnace, carbon(II) oxide (COCO) gas is produced when hot carbon dioxide reacts with excess coke. Rising COCO gas encounters descending hematite (Fe2O3Fe_2O_3) in the upper, cooler zone of the furnace and reduces it to iron: Fe2O3(s)+3CO(g)2Fe(s)+3CO2(g)Fe_2O_3(s) + 3CO(g) \rightarrow 2Fe(s) + 3CO_2(g).

Step-by-Step Solution

1
Identify the chemical reactions occurring in the upper region of the blast furnace.
Near the top of the furnace (200°C–700°C), carbon(II) oxide gas reacts with descending hematite ore.
Gas-solid contact allows COCO to easily reduce the porous iron ore.
2
Write the overall reduction equation.
Fe2O3(s)+3CO(g)2Fe(s)+3CO2(g)Fe_2O_3(s) + 3CO(g) \rightarrow 2Fe(s) + 3CO_2(g)
This chemical equation confirms that COCO gains oxygen (is oxidized) while reducing Fe2O3Fe_2O_3 to metallic iron.

Key Concept

Role of gaseous carbon(II) oxide as the principal reducing agent in blast furnace iron extraction
Estimated Time:45s
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