Question

Difficulty: MediumBoyle's Law and Pressure-Volume Relationship

A weather balloon inflated with helium has a volume of 5.0 dm35.0\text{ dm}^3 at ground level where the atmospheric pressure is 100 kPa100\text{ kPa} and the temperature is 27C27^\circ\text{C}. The balloon ascends to an altitude where the ambient pressure drops to 40 kPa40\text{ kPa}. Assuming isothermal conditions are maintained throughout the ascent, what is the new volume of the helium gas in the balloon?

  1. 12.5 dm312.5\text{ dm}^3Answer
  2. B
    2.0 dm32.0\text{ dm}^3
  3. C
    1.125 dm31.125\text{ dm}^3
  4. D
    8.0 dm38.0\text{ dm}^3

Answer

12.5 dm312.5\text{ dm}^3
Boyle's Law states that for a fixed mass of gas at constant temperature, the volume is inversely proportional to the pressure (P1V1=P2V2P_1 V_1 = P_2 V_2). Substituting the initial pressure of 100 kPa100\text{ kPa}, initial volume of 5.0 dm35.0\text{ dm}^3, and final pressure of 40 kPa40\text{ kPa} gives V2=(100×5.0)/40=12.5 dm3V_2 = (100 \times 5.0) / 40 = 12.5\text{ dm}^3.

Step-by-Step Solution

1
Identify the given parameters and constant conditions
P1=100 kPaP_1 = 100\text{ kPa}, V1=5.0 dm3V_1 = 5.0\text{ dm}^3, P2=40 kPaP_2 = 40\text{ kPa}. Temperature is constant (isothermal condition).
Boyle's Law applies when a fixed mass of gas is kept at a constant temperature.
2
State Boyle's Law formula
P1V1=P2V2P_1 V_1 = P_2 V_2
Pressure and volume of a fixed mass of ideal gas are inversely proportional at constant temperature.
3
Rearrange the formula to solve for the unknown final volume (V2V_2)
V2=P1V1P2V_2 = \frac{P_1 V_1}{P_2}
Isolating V2V_2 allows direct substitution of known variables.
4
Substitute the given numerical values into the equation and calculate
V2=100 kPa×5.0 dm340 kPa=50040=12.5 dm3V_2 = \frac{100\text{ kPa} \times 5.0\text{ dm}^3}{40\text{ kPa}} = \frac{500}{40} = 12.5\text{ dm}^3
Units of pressure (kPa\text{kPa}) cancel out, leaving the volume in dm3\text{dm}^3.

Key Concept

Boyle's Law (P1V1=P2V2P_1 V_1 = P_2 V_2 at constant temperature)
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