Question

Difficulty: EasyFunctional Groups, Homologous Series, and IUPAC Nomenclature

Match each characteristic functional group structure listed on the left with its corresponding organic class name on the right.

  • −NH2-\text{NH}_2Primary amine
  • −CONH2-\text{CONH}_2Amide
  • −O−-\text{O}-Ether
  • −COOR-\text{COOR}Ester

Answer

The correct pairings are: −NH2-\text{NH}_2 matches with Primary amine, −CONH2-\text{CONH}_2 matches with Amide, −O−-\text{O}- matches with Ether, and −COOR-\text{COOR} matches with Ester.
Each organic compound class is identified by its specific functional group arrangement: −NH2-\text{NH}_2 specifies primary amines, −CONH2-\text{CONH}_2 specifies primary amides, an oxygen atom bridging two carbon groups (−O−-\text{O}-) specifies ethers, and −COOR-\text{COOR} specifies esters.

Step-by-Step Solution

1
Identify the amino functional group
−NH2-\text{NH}_2 is recognized as an amino group attached to a carbon chain.
Compounds containing the −NH2-\text{NH}_2 group attached directly to an alkyl carbon belong to the class of primary amines.
2
Identify the carboxamide functional group
−CONH2-\text{CONH}_2 contains a carbonyl bonded to an amino group.
This structural unit defines the primary amide family.
3
Identify the ether linkage
−O−-\text{O}- represents a single oxygen atom bridging two carbon atoms.
An oxygen atom connected to two alkyl or aryl groups (R-O-R’\text{R-O-R'}) characterizes an ether.
4
Identify the ester group
−COOR-\text{COOR} contains a carbonyl carbon attached to an alkoxy group.
This group is derived from an alkanoic acid and an alkanol, forming an ester.

Key Concept

Identification of characteristic functional groups in organic compounds
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