Question

Difficulty: Very hardLatent Heat and Changes of State

In an experiment to determine the specific latent heat of vaporization of water at 100C100^\circ\text{C} using an electric immersion heater in an uninsulated vessel, if heat loss from the vessel to the cooler surrounding environment is neglected in the calculations, the experimentally determined value of the specific latent heat of vaporization will be higher than the true value.

Answer: Answer

Answer

True
The statement is correct because the measured energy supplied by the heater includes both the energy required for the phase change and the thermal energy dissipated to the surroundings. Dividing this larger total energy by the mass of vaporized liquid results in an overestimation of the specific latent heat of vaporization.

Step-by-Step Solution

1
Formulate the thermal energy balance equation including heat loss.
Qelectrical=Qvaporization+QlossQ_{\text{electrical}} = Q_{\text{vaporization}} + Q_{\text{loss}}, where Qelectrical=PtQ_{\text{electrical}} = P \cdot t and Qvaporization=mLtrueQ_{\text{vaporization}} = m \cdot L_{\text{true}}.
Energy conservation dictates that the electrical energy supplied by the heater equals the thermal energy used for vaporization plus the heat lost to the cooler ambient surroundings.
2
Express the calculated specific latent heat LcalcL_{\text{calc}} under the assumption of zero heat loss.
Lcalc=Qelectricalm=mLtrue+QlossmL_{\text{calc}} = \frac{Q_{\text{electrical}}}{m} = \frac{m \cdot L_{\text{true}} + Q_{\text{loss}}}{m}.
The experimenter measures the total electrical power and time, assuming all of this energy converted liquid into vapor.
3
Compare the calculated specific latent heat LcalcL_{\text{calc}} with the true value LtrueL_{\text{true}}.
Lcalc=Ltrue+Qlossm>LtrueL_{\text{calc}} = L_{\text{true}} + \frac{Q_{\text{loss}}}{m} > L_{\text{true}}.
Because Qloss>0Q_{\text{loss}} > 0 and mass m>0m > 0, the ratio Qlossm\frac{Q_{\text{loss}}}{m} is positive, meaning LcalcL_{\text{calc}} is higher than LtrueL_{\text{true}}.

Key Concept

Experimental Heat Loss Error Propagation in Latent Heat Calculations
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