Question

Difficulty: MediumThe Mole Concept, Avogadro's Constant, and Molar Mass

A sample of pure ammonia gas (NH3\text{NH}_3) has a mass of 3.4 g3.4\text{ g}. What is the total number of atoms contained in this sample? [N=14,H=1,NA=6.02×1023 mol1][\text{N} = 14, \text{H} = 1, N_A = 6.02 \times 10^{23}\text{ mol}^{-1}]

  1. 4.816×10234.816 \times 10^{23}Answer
  2. B
    1.204×10231.204 \times 10^{23}
  3. C
    3.612×10233.612 \times 10^{23}
  4. D
    2.408×10232.408 \times 10^{23}

Answer

4.816×10234.816 \times 10^{23} atoms
The molar mass of ammonia (NH3\text{NH}_3) is 17 g/mol17\text{ g/mol}. A mass of 3.4 g3.4\text{ g} corresponds to 0.2 moles0.2\text{ moles} of NH3\text{NH}_3 molecules, which contains 1.204×10231.204 \times 10^{23} molecules. Because one molecule of NH3\text{NH}_3 consists of 44 atoms (11 nitrogen atom and 33 hydrogen atoms), multiplying 1.204×10231.204 \times 10^{23} by 44 gives 4.816×10234.816 \times 10^{23} total atoms.

Step-by-Step Solution

1
Calculate the molar mass of ammonia (NH3\text{NH}_3)
Molar Mass=14+3(1)=17 g/mol\text{Molar Mass} = 14 + 3(1) = 17\text{ g/mol}
Molar mass is required to convert sample mass into moles.
2
Calculate the number of moles of NH3\text{NH}_3
Moles=3.4 g17 g/mol=0.2 mol\text{Moles} = \frac{3.4\text{ g}}{17\text{ g/mol}} = 0.2\text{ mol}
Dividing given mass by molar mass yields the mole quantity.
3
Determine the number of molecules of NH3\text{NH}_3
Molecules=0.2 mol×6.02×1023 mol1=1.204×1023 molecules\text{Molecules} = 0.2\text{ mol} \times 6.02 \times 10^{23}\text{ mol}^{-1} = 1.204 \times 10^{23}\text{ molecules}
Multiplying moles by Avogadro's constant gives total molecules.
4
Calculate the total number of individual atoms
Total atoms=1.204×1023×4=4.816×1023 atoms\text{Total atoms} = 1.204 \times 10^{23} \times 4 = 4.816 \times 10^{23}\text{ atoms}
Each NH3\text{NH}_3 molecule contains 1 nitrogen atom and 3 hydrogen atoms (4 atoms in total).

Key Concept

Converting mass to number of constituent atoms using Avogadro's constant and molecular stoichiometry.
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