Question

Difficulty: MediumAtomic Models

In Bohr's model of the hydrogen atom, the radius of a stationary orbit is proportional to n2n^2, where nn is the principal quantum number. If the radius of the ground-state orbit (n=1n = 1) is r1r_1, what is the radius of the orbit corresponding to the second excited state?

  1. A
    3r13r_1
  2. B
    4r14r_1
  3. C
    6r16r_1
  4. 9r19r_1Answer

Answer

The radius of the electron's orbit in the second excited state is 9r19r_1.
In Bohr's atomic model, the ground state corresponds to the quantum number n=1n = 1. The excited states are numbered sequentially above the ground state: the first excited state is n=2n = 2 and the second excited state is n=3n = 3. Since the orbital radius scales with the square of the principal quantum number (rn=n2r1r_n = n^2 r_1), substituting n=3n = 3 yields r3=32r1=9r1r_3 = 3^2 r_1 = 9r_1. Thus, the option stating 9r19r_1 is correct.

Step-by-Step Solution

1
Identify the principal quantum number nn for the second excited state.
n=3n = 3
The ground state corresponds to n=1n = 1, the first excited state corresponds to n=2n = 2, and the second excited state corresponds to n=3n = 3.
2
Apply Bohr's radius formula for hydrogen-like atoms.
rn=n2r1r_n = n^2 r_1
According to Bohr's postulates, the orbital radius is proportional to the square of the principal quantum number nn.
3
Calculate r3r_3 by substituting n=3n = 3 into the radius expression.
r3=32r1=9r1r_3 = 3^2 r_1 = 9r_1
Squaring n=3n = 3 gives 99, making the radius 9 times the ground-state radius.

Key Concept

Bohr's quantization of orbital radius (rnn2r_n \propto n^2)
Estimated Time:1m 0s
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