Question

Difficulty: EasyAlloys: Classification, Compositions, Physical Properties, and Uses

Alloys are frequently used in structural engineering and manufacturing because they exhibit greater mechanical strength and hardness than pure metals. Which of the following structural factors best explains why introducing a secondary element increases the hardness of a metal?

  1. Atoms of differing sizes disrupt the regular crystal lattice, hindering the movement of atomic layers past one another.Answer
  2. B
    The constituent elements undergo a chemical reaction to form rigid giant covalent networks throughout the solid.
  3. C
    Delocalized valence electrons are completely removed, converting the metallic lattice into an ionic crystal structure.
  4. D
    The added atoms expand in volume to completely fill all interatomic spaces and stop thermal vibrations.

Answer

Atoms of differing sizes disrupt the regular crystal lattice, hindering the movement of atomic layers past one another.
In a pure metal, identical atoms form regular layers that slip over one another with relative ease. When a secondary element with a different atomic radius is introduced to form an alloy, the regular lattice arrangement is distorted. This disruption prevents atomic layers from sliding smoothly, significantly increasing the hardness and tensile strength of the alloy.

Step-by-Step Solution

1
Consider the structure of a pure metal.
In pure metals, identical atoms are arranged in uniform, orderly layers that easily slide over each other under shear stress, making the metal malleable and relatively soft.
Uniform atomic radii allow smooth plane slipping along lattice planes.
2
Analyze the structural effect of alloying.
Adding atoms of a different size introduces structural irregularities and distorts the host crystal lattice.
The distortion creates friction and resistance against the sliding of atomic layers, resulting in enhanced hardness and strength.

Key Concept

Lattice distortion and mechanical strengthening of alloys
Estimated Time:45s
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