Question

Difficulty: EasyChemical Equations and Stoichiometric Calculations (Mass-Mass, Mass-Volume, Mole Relations)
What volume of hydrogen gas measured at s.t.p. is evolved when 13.0 g13.0\text{ g} of pure zinc completely reacts with excess dilute hydrochloric acid according to the equation below?
Zn(s)+2HCl(aq)ZnCl2(aq)+H2(g)\text{Zn}(s) + 2\text{HCl}(aq) \rightarrow \text{ZnCl}_2(aq) + \text{H}_2(g)
[Zn=65,Molar gas volume at s.t.p.=22.4 dm3 mol1][\text{Zn} = 65, \text{Molar gas volume at s.t.p.} = 22.4\text{ dm}^3\text{ mol}^{-1}]
  1. 4.48 dm34.48\text{ dm}^3Answer
  2. B
    4.80 dm34.80\text{ dm}^3
  3. C
    8.96 dm38.96\text{ dm}^3
  4. D
    2.24 dm32.24\text{ dm}^3

Answer

4.48 dm34.48\text{ dm}^3
The balanced chemical equation indicates a 1:1 molar relationship between zinc and hydrogen gas. Reacting 13.0 g13.0\text{ g} of zinc corresponds to 13.065=0.20 mol\frac{13.0}{65} = 0.20\text{ mol} of zinc, yielding 0.20 mol0.20\text{ mol} of hydrogen gas. Multiplying by the molar volume at s.t.p. (22.4 dm3 mol122.4\text{ dm}^3\text{ mol}^{-1}) gives 0.20×22.4=4.48 dm30.20 \times 22.4 = 4.48\text{ dm}^3.

Step-by-Step Solution

1
Calculate the number of moles of zinc reacted
Moles of Zn=13.0 g65 g mol1=0.20 mol\text{Moles of Zn} = \frac{13.0\text{ g}}{65\text{ g mol}^{-1}} = 0.20\text{ mol}
Converting given mass of reactant to moles using relative atomic mass.
2
Determine the moles of hydrogen gas produced from the balanced equation
Mole ratio of Zn to H2=1:1\text{Mole ratio of Zn to H}_2 = 1 : 1, so moles of H2=0.20 mol\text{moles of H}_2 = 0.20\text{ mol}
Applying mole ratio constraints from the chemical equation.
3
Calculate the volume of hydrogen gas at s.t.p.
Volume of H2=0.20 mol×22.4 dm3 mol1=4.48 dm3\text{Volume of H}_2 = 0.20\text{ mol} \times 22.4\text{ dm}^3\text{ mol}^{-1} = 4.48\text{ dm}^3
Multiplying moles of gas by standard molar volume at s.t.p.

Key Concept

Mass-Volume stoichiometric calculation at standard temperature and pressure (s.t.p.)
Estimated Time:1m 0s
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