Question

Difficulty: MediumChemistry in Daily Life and Industrial Applications

Safety matches rely on specific chemical formulations on both the match head and the striking surface to ensure controlled ignition. Which of the following statements regarding the chemical composition and functions of components in safety matches are correct?

  1. Potassium chlorate (KClO3KClO_3) is present in the match head to serve as an oxidizing agent that decomposes to supply oxygen during friction.Answer
  2. The striking surface of a safety matchbox contains red phosphorus, which undergoes friction-induced conversion to ignite the match.Answer
  3. Antimony trisulfide (Sb2S3Sb_2S_3) is incorporated into the match head to function as a combustible fuel.Answer
  4. D
    White phosphorus is applied directly to the striking surface of modern safety matches because of its chemical stability and non-toxic nature.

Answer

The correct statements are those identifying potassium chlorate as the oxidizing agent in the match head, red phosphorus on the striking strip as the ignition initiator, and antimony trisulfide as the fuel in the match head.
The statements correctly identify that potassium chlorate acts as an oxidizing agent in the match head, antimony trisulfide functions as the fuel in the head, and red phosphorus on the striking surface initiates combustion via friction-induced heat.

Step-by-Step Solution

1
Analyze the chemical composition of the match head.
The match head contains potassium chlorate (KClO3KClO_3) as an oxidizing agent, antimony trisulfide (Sb2S3Sb_2S_3) as a fuel, and a binder/glue.
Potassium chlorate decomposes to yield oxygen, which rapidly oxidizes antimony trisulfide to sustain the flame.
2
Examine the composition and reaction of the striking surface.
The striking surface contains red phosphorus, powdered glass (an abrasive/friction agent), and adhesive.
Striking generates frictional heat, transforming a minute portion of stable red phosphorus into reactive white phosphorus vapor that ignites.
3
Evaluate the safety hazard associated with white phosphorus.
White phosphorus (P4P_4) is poisonous and ignites spontaneously in air at room temperature.
It was banned internationally under the Berne Convention of 1906 due to severe occupational toxicity ('phossy jaw') and spontaneous combustion hazards.

Key Concept

Chemical Composition and Reaction Dynamics of Safety Matches
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