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Zorluk: OrtaIron: Blast Furnace Extraction, Rusting Prevention, and Chemical Compounds

When iron filings are heated in a stream of dry chlorine gas, compound XX is formed. Conversely, when iron filings react with dilute hydrochloric acid, compound YY is produced. What are the correct IUPAC names of compounds XX and YY respectively?

  1. Iron(III) chloride and iron(II) chlorideCevap
  2. B
    Iron(II) chloride and iron(III) chloride
  3. C
    Iron(III) chloride and iron(III) chloride
  4. D
    Iron(II) chloride and iron(II) chloride

Cevap

Iron(III) chloride and iron(II) chloride
Dry chlorine gas acts as a powerful oxidizing agent that oxidizes iron directly to iron(III) chloride (FeCl3\text{FeCl}_3). In contrast, reacting iron with dilute hydrochloric acid generates iron(II) chloride (FeCl2\text{FeCl}_2) because the evolved hydrogen gas acts as a reducing agent, maintaining iron in the +2+2 oxidation state.

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1
Analyze the reaction of iron with dry chlorine gas
2Fe(s)+3Cl2(g)2FeCl3(s)2\text{Fe}_{(s)} + 3\text{Cl}_{2(g)} \rightarrow 2\text{FeCl}_{3(s)}
Chlorine gas is a powerful oxidizing agent capable of taking iron from oxidation state 0 to +3, forming iron(III) chloride.
2
Analyze the reaction of iron with dilute hydrochloric acid
\text{Fe}_{(s)} + 2\text{HCl}_{(aq)} \rightarrow \text{FeCl}_{2(aq)} + \text{H}_{2(g)}
Dilute hydrochloric acid oxidizes iron to iron(II) chloride (+2+2 state). The hydrogen gas (H2\text{H}_2) evolved during the reaction acts as a reducing agent, preventing any further oxidation to iron(III).
3
Match the products to compound XX and compound YY
Compound XX is iron(III) chloride and compound YY is iron(II) chloride.
Sequential identification following the given stem conditions.

Anahtar Kavram

Variable oxidation states of iron and differential oxidizing strength of chlorine versus hydrogen ions.
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