During the fractional distillation of liquid air, nitrogen gas boils off at prior to oxygen gas at because liquid air is a homogeneous mixture whose constituent substances retain their individual physical properties.
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The statement is TRUE.
Liquid air behaves as a physical mixture rather than a chemical compound. Consequently, its components retain their individual physical constants. Nitrogen boils off at before oxygen at during fractional distillation precisely because the mixture does not have a single fixed compound boiling point and its components maintain their independent identities.
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Retention of individual physical properties by components of a mixture vs. chemical compounds
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