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Zorluk: Çok zorAtomic Models

In a hydrogen atom modeled according to Bohr's postulates, an electron undergoes a transition from an initial excited state nn to the ground state n=1n=1, emitting a photon whose wavelength is λ=1615R\lambda = \frac{16}{15R}, where RR is the Rydberg constant. What is the orbital angular momentum of the electron in its initial excited state prior to the transition?

  1. A
    h2π\frac{h}{2\pi}
  2. B
    hπ\frac{h}{\pi}
  3. 2hπ\frac{2h}{\pi}Cevap
  4. D
    4hπ\frac{4h}{\pi}

Cevap

2hπ\frac{2h}{\pi}
Using the Rydberg formula 1λ=R(1121n2)\frac{1}{\lambda} = R \left( \frac{1}{1^2} - \frac{1}{n^2} \right) with λ=1615R\lambda = \frac{16}{15R}, we find 1516=11n2\frac{15}{16} = 1 - \frac{1}{n^2}, which gives n=4n = 4. By Bohr's angular momentum quantization condition, L=nh2π=4h2π=2hπL = \frac{nh}{2\pi} = \frac{4h}{2\pi} = \frac{2h}{\pi}.

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1
Apply the Rydberg formula for hydrogen to determine the principal quantum number nn of the initial state.
1λ=R(1121n2)    15R16=R(11n2)    11n2=1516    1n2=116    n=4\frac{1}{\lambda} = R \left( \frac{1}{1^2} - \frac{1}{n^2} \right) \implies \frac{15R}{16} = R \left( 1 - \frac{1}{n^2} \right) \implies 1 - \frac{1}{n^2} = \frac{15}{16} \implies \frac{1}{n^2} = \frac{1}{16} \implies n = 4.
The Rydberg formula links the photon wavelength emitted during a transition between energy levels to the principal quantum numbers.
2
Calculate the orbital angular momentum LL for n=4n=4 using Bohr's quantization condition.
L=nh2π=4h2π=2hπL = \frac{n h}{2\pi} = \frac{4 h}{2\pi} = \frac{2 h}{\pi}.
Bohr's quantization postulate dictates that orbital angular momentum is an integral multiple of h2π\frac{h}{2\pi}.

Anahtar Kavram

Bohr's Atomic Model: Spectral transitions and angular momentum quantization
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