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Zorluk: OrtaSubatomic Particles, Atomic Number, Mass Number, and Isotopy

Element EE has a relative atomic mass of 12.01112.011 and exists as two naturally occurring isotopes: 12E^{12}\text{E} with a natural abundance of 98.9%98.9\% and AE^{A}\text{E} with a natural abundance of 1.1%1.1\%. What is the mass number (AA) of the second isotope?

Cevap: 13

Cevap

The mass number of the second isotope is 13.
Relative atomic mass is calculated as the weighted average of the mass numbers of all naturally occurring isotopes. Setting up the equation 12.011=(98.9×12)+(1.1×A)10012.011 = \frac{(98.9 \times 12) + (1.1 \times A)}{100} yields 1201.1=1186.8+1.1A1201.1 = 1186.8 + 1.1A, which simplifies to 1.1A=14.31.1A = 14.3 and gives A=13A = 13.

Adım Adım Çözüm

1
State the relationship for relative atomic mass based on isotopic abundance.
RAM=(Abundance1×Mass1)+(Abundance2×Mass2)100\text{RAM} = \frac{(\text{Abundance}_1 \times \text{Mass}_1) + (\text{Abundance}_2 \times \text{Mass}_2)}{100}
Relative atomic mass is the weighted average of the atomic masses of naturally occurring isotopes of an element.
2
Substitute the given numerical values into the formula.
12.011=(98.9×12)+(1.1×A)10012.011 = \frac{(98.9 \times 12) + (1.1 \times A)}{100}
Inserting the known abundances (98.9%98.9\% and 1.1%1.1\%) and mass number (1212) sets up an algebraic equation for the unknown mass number AA.
3
Solve the algebraic equation for AA.
1201.1=1186.8+1.1A    1.1A=14.3    A=131201.1 = 1186.8 + 1.1A \implies 1.1A = 14.3 \implies A = 13
Subtracting the contribution of the first isotope and dividing by the abundance of the second isotope gives the integer mass number 1313.

Anahtar Kavram

Calculating isotopic mass number from relative atomic mass and fractional abundances
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