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Zorluk: ZorComposition and Pollution of Air

A 500 cm3500\text{ cm}^3 sample of air collected near an industrial plant containing nitrogen (N2\text{N}_2), oxygen (O2\text{O}_2), carbon dioxide (CO2\text{CO}_2), and sulfur dioxide (SO2\text{SO}_2) pollutant was passed through concentrated potassium hydroxide (KOH\text{KOH}) solution, reducing the gas volume to 485 cm3485\text{ cm}^3. The residual gas mixture was subsequently passed through excess alkaline solution of pyrogallol, resulting in a final volume of 383 cm3383\text{ cm}^3. What is the percentage by volume of oxygen in the original air sample?

Cevap: 20.4 %

Cevap

20.4%
Concentrated potassium hydroxide (KOH) absorbs the acidic gas pollutants (carbon dioxide and sulfur dioxide), causing an initial volume contraction of 15 cm315\text{ cm}^3. Alkaline pyrogallol then absorbs elemental oxygen gas (O2\text{O}_2), causing a further contraction from 485 cm3485\text{ cm}^3 to 383 cm3383\text{ cm}^3, which corresponds to 102 cm3102\text{ cm}^3 of O2\text{O}_2. Dividing this volume of oxygen by the original total sample volume of 500 cm3500\text{ cm}^3 and multiplying by 100%100\% yields 20.4%20.4\%.

Adım Adım Çözüm

1
Identify the volume reduction caused by potassium hydroxide (KOH)
KOH absorbs acidic gases CO₂ and SO₂: 500 cm3485 cm3=15 cm3500\text{ cm}^3 - 485\text{ cm}^3 = 15\text{ cm}^3.
Potassium hydroxide is an alkaline reagent that selectively absorbs acidic oxides present in polluted air.
2
Determine the volume of oxygen gas absorbed by alkaline pyrogallol
Alkaline pyrogallol absorbs O₂: 485 cm3383 cm3=102 cm3485\text{ cm}^3 - 383\text{ cm}^3 = 102\text{ cm}^3.
Alkaline pyrogallol is a specific quantitative reagent used to absorb unreacted oxygen gas.
3
Calculate the percentage volume of oxygen in the initial sample
(102 cm3500 cm3)×100%=20.4%\left(\frac{102\text{ cm}^3}{500\text{ cm}^3}\right) \times 100\% = 20.4\%.
The volume percentage of a component in air is the ratio of its volume to the total initial unreacted air sample volume multiplied by 100.

Anahtar Kavram

Quantitative volumetric determination of atmospheric components and gaseous pollutants using selective absorbents
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