A sample of air collected near an industrial plant containing nitrogen (), oxygen (), carbon dioxide (), and sulfur dioxide () pollutant was passed through concentrated potassium hydroxide () solution, reducing the gas volume to . The residual gas mixture was subsequently passed through excess alkaline solution of pyrogallol, resulting in a final volume of . What is the percentage by volume of oxygen in the original air sample?
Cevap: 20.4 %
Cevap
20.4%
Concentrated potassium hydroxide (KOH) absorbs the acidic gas pollutants (carbon dioxide and sulfur dioxide), causing an initial volume contraction of . Alkaline pyrogallol then absorbs elemental oxygen gas (), causing a further contraction from to , which corresponds to of . Dividing this volume of oxygen by the original total sample volume of and multiplying by yields .
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Anahtar Kavram
Quantitative volumetric determination of atmospheric components and gaseous pollutants using selective absorbents
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