Question

Difficulty: MediumLaws of Chemical Combination (Conservation of Mass, Definite & Multiple Proportions)

A 4.00 g4.00\text{ g} sample of a copper oxide is completely reduced by dry hydrogen gas to yield 3.20 g3.20\text{ g} of metallic copper. According to the Law of Definite Proportions, what mass of this same copper oxide, in grams, will be produced when 5.00 g5.00\text{ g} of pure copper is completely oxidized?

Answer: 6.25 g

Answer

6.25 g
According to the Law of Definite Proportions (or Constant Composition), a chemical compound always contains its component elements in fixed mass ratios. In the first sample, copper makes up 3.20 g/4.00 g=0.803.20\text{ g} / 4.00\text{ g} = 0.80 or 80%80\% of the total mass. Therefore, in any sample of this oxide, 5.00 g5.00\text{ g} of copper represents 80%80\% of the total mass. Dividing 5.00 g5.00\text{ g} by 0.800.80 gives 6.25 g6.25\text{ g} of copper oxide.

Step-by-Step Solution

1
Determine the mass percentage (or mass fraction) of copper in the compound from the first experiment
Mass fraction of Cu = 3.20 / 4.00 = 0.80 (80%)
The first experiment provides quantitative data regarding the mass of copper contained in a known mass of oxide.
2
Apply the Law of Definite Proportions to calculate the required mass of copper oxide for 5.00 g of copper
Mass of Copper Oxide = 5.00 / 0.80 = 6.25 g
The Law of Definite Proportions dictates that the mass composition ratio remains constant regardless of the sample source or size.

Key Concept

Law of Definite Proportions
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