Question

Difficulty: MediumLaws of Chemical Combination (Conservation of Mass, Definite & Multiple Proportions)

A sample of pure methane (CH4\text{CH}_4) contains 3.00 g3.00\text{ g} of carbon. When this sample undergoes complete combustion in excess oxygen gas, all the hydrogen present is converted into water vapor (H2O\text{H}_2\text{O}). Based on the Law of Definite Proportions, what is the total mass (in grams) of water vapor produced? [Atomic masses: H=1\text{H} = 1, C=12\text{C} = 12, O=16\text{O} = 16]

Answer: 9 g

Answer

The total mass of water vapor produced is 9.00 g9.00\text{ g}.
According to the Law of Definite Proportions, a chemical compound always contains its component elements in a fixed ratio by mass. In methane (CH4\text{CH}_4), the ratio of mass of carbon to hydrogen is 12:412 : 4 (3:13 : 1). Therefore, 3.00 g3.00\text{ g} of carbon is combined with 1.00 g1.00\text{ g} of hydrogen. When methane undergoes complete combustion, all 1.00 g1.00\text{ g} of hydrogen is converted into water (H2O\text{H}_2\text{O}). Since hydrogen makes up 218\frac{2}{18} of the mass of water, 1.00 g1.00\text{ g} of hydrogen yields 1.00×182=9.00 g1.00 \times \frac{18}{2} = 9.00\text{ g} of water.

Step-by-Step Solution

1
Calculate the mass of hydrogen present in the methane sample using the Law of Definite Proportions.
The mass of hydrogen in the sample is 1.00 g1.00\text{ g}.
In CH4\text{CH}_4, the mass ratio of carbon to hydrogen is 12:4=3:112 : 4 = 3 : 1. Given 3.00 g3.00\text{ g} of carbon, the mass of hydrogen is 3.00 g3=1.00 g\frac{3.00\text{ g}}{3} = 1.00\text{ g}.
2
Determine the mass fraction of hydrogen in water (H2O\text{H}_2\text{O}).
Hydrogen accounts for 218\frac{2}{18} of the total mass of water.
The molar mass of H2O\text{H}_2\text{O} is 2(1)+16=18 g/mol2(1) + 16 = 18\text{ g/mol}, of which 2 g2\text{ g} is hydrogen.
3
Calculate the total mass of water vapor formed from the hydrogen.
The total mass of water produced is 9.00 g9.00\text{ g}.
All 1.00 g1.00\text{ g} of hydrogen from methane is converted into water. Mass of H2O=1.00 g×182=9.00 g\text{H}_2\text{O} = 1.00\text{ g} \times \frac{18}{2} = 9.00\text{ g}.

Key Concept

Law of Definite Proportions (Constant Composition)
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