Question

Difficulty: MediumChemical Equations and Stoichiometric Calculations (Mass-Mass, Mass-Volume, Mole Relations)
Consider the balanced chemical equation for the complete combustion of ethane gas:
2C2H6(g)+7O2(g)4CO2(g)+6H2O(g)2C_2H_6(g) + 7O_2(g) \rightarrow 4CO_2(g) + 6H_2O(g)
What volume of oxygen gas, measured at STP, is required to react completely with 0.5 mol0.5\text{ mol} of ethane? Complete the statement below with the calculated numerical value.
Answer:The volume of oxygen gas required at STP is 【39.2】 dm3\text{dm}^3. (Molar gas volume at STP = 22.4 dm3mol122.4\text{ dm}^3\text{mol}^{-1})

Answer

39.2 dm³ (or 39.2)
According to the balanced equation 2C2H6(g)+7O2(g)4CO2(g)+6H2O(g)2C_2H_6(g) + 7O_2(g) \rightarrow 4CO_2(g) + 6H_2O(g), 2 moles2\text{ moles} of ethane require 7 moles7\text{ moles} of oxygen gas for complete combustion. Therefore, 0.5 mol0.5\text{ mol} of ethane requires 0.5×72=1.75 mol\frac{0.5 \times 7}{2} = 1.75\text{ mol} of oxygen gas. At standard temperature and pressure (STP), 1 mole1\text{ mole} of gas occupies 22.4 dm322.4\text{ dm}^3. Thus, the volume of oxygen gas required is 1.75 mol×22.4 dm3mol1=39.2 dm31.75\text{ mol} \times 22.4\text{ dm}^3\text{mol}^{-1} = 39.2\text{ dm}^3.

Step-by-Step Solution

1
Identify the stoichiometric mole ratio between ethane and oxygen from the balanced equation
From 2C2H6+7O22C_2H_6 + 7O_2, the mole ratio of C2H6C_2H_6 to O2O_2 is 2:72 : 7.
Stoichiometric coefficients represent the relative mole proportions of reactants.
2
Calculate the moles of oxygen gas needed for 0.5 mol of ethane
Moles of O2=0.5 mol×72=1.75 molO_2 = 0.5\text{ mol} \times \frac{7}{2} = 1.75\text{ mol}
Multiplying the given amount of ethane by the stoichiometric factor gives the required moles of oxygen.
3
Convert the calculated moles of oxygen gas to volume at STP
Volume of O2=1.75 mol×22.4 dm3mol1=39.2 dm3O_2 = 1.75\text{ mol} \times 22.4\text{ dm}^3\text{mol}^{-1} = 39.2\text{ dm}^3
One mole of any ideal gas occupies 22.4 dm322.4\text{ dm}^3 at STP.

Key Concept

Mole-Volume Stoichiometric Calculations at STP
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