Question

Difficulty: MediumVapour Pressure, Boiling, Evaporation, and Relative Humidity

The saturated vapour pressure of water in an enclosed space is 25 mmHg25\text{ mmHg}. If the relative humidity within the space is measured to be 64%64\%, what is the partial pressure of the water vapour in mmHg\text{mmHg}?

Answer: 16 mmHg

Answer

The partial pressure of the water vapour in the enclosed space is 16 mmHg16\text{ mmHg}.
Relative humidity is defined as the ratio of the actual partial pressure of water vapour present in a given volume of air to the saturated vapour pressure at the same temperature, expressed as a percentage: R.H.=PS.V.P.×100%\text{R.H.} = \frac{P}{\text{S.V.P.}} \times 100\%. Rearranging this equation gives P=R.H.×S.V.P.100=64×25100=16 mmHgP = \frac{\text{R.H.} \times \text{S.V.P.}}{100} = \frac{64 \times 25}{100} = 16\text{ mmHg}.

Step-by-Step Solution

1
Identify the given parameters and state the relative humidity formula.
Relative Humidity (R.H.) = 64%64\%, Saturated Vapour Pressure (S.V.P.) = 25 mmHg25\text{ mmHg}. R.H.=PS.V.P.×100%\text{R.H.} = \frac{P}{\text{S.V.P.}} \times 100\%.
Relative humidity relates the actual partial vapour pressure present to the maximum saturated vapour pressure possible at that temperature.
2
Substitute the values into the equation and solve for partial pressure PP.
64=P25×100    64=4P    P=16 mmHg64 = \frac{P}{25} \times 100 \implies 64 = 4P \implies P = 16\text{ mmHg}.
Dividing 100100 by 2525 yields a factor of 44, allowing clean mental computation.

Key Concept

Relationship between relative humidity, partial vapour pressure, and saturated vapour pressure.
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