Question

Difficulty: MediumVapour Pressure, Boiling, Evaporation, and Relative Humidity

On a warm day, the saturated vapour pressure of water at an ambient temperature of 25C25^\circ\text{C} is 24 mmHg24\text{ mmHg}. If the actual partial pressure of water vapour in the air at this temperature is 18 mmHg18\text{ mmHg}, what is the relative humidity of the atmosphere?

  1. 75%75\%Answer
  2. B
    133%133\%
  3. C
    25%25\%
  4. D
    43%43\%

Answer

The relative humidity of the atmosphere is 75%75\%.
The relative humidity is defined as the ratio of the partial vapour pressure of water present in the air to the saturated vapour pressure at the ambient temperature, expressed as a percentage. Dividing 18 mmHg18\text{ mmHg} by 24 mmHg24\text{ mmHg} yields 0.750.75, which equals 75%75\%.

Step-by-Step Solution

1
Identify the formula for relative humidity.
Relative Humidity=(Partial Vapour PressureSaturated Vapour Pressure at same temp)×100%\text{Relative Humidity} = \left(\frac{\text{Partial Vapour Pressure}}{\text{Saturated Vapour Pressure at same temp}}\right) \times 100\%
Relative humidity measures how close atmospheric air is to saturation at a given temperature.
2
Substitute the given values into the formula.
Relative Humidity=(18 mmHg24 mmHg)×100%\text{Relative Humidity} = \left(\frac{18\text{ mmHg}}{24\text{ mmHg}}\right) \times 100\%
The partial pressure is 18 mmHg18\text{ mmHg} and the saturated vapour pressure is 24 mmHg24\text{ mmHg}.
3
Calculate the final percentage.
Relative Humidity=0.75×100%=75%\text{Relative Humidity} = 0.75 \times 100\% = 75\%
Simplifying 1824\frac{18}{24} gives 34\frac{3}{4}, which corresponds to 0.750.75 or 75%75\%.

Key Concept

Relative humidity is the ratio of the actual mass (or partial pressure) of water vapour in a given volume of air to the maximum mass (or saturated vapour pressure) of water vapour that the same volume of air can hold at that same temperature, expressed as a percentage.
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