Question

Difficulty: HardSubatomic Particles, Atomic Number, Mass Number, and Isotopy

Element XX exists naturally as three isotopes with mass numbers 2424, 2525, and 2626. The relative atomic mass of element XX is 24.3224.32. If the natural abundance of the isotope 25X^{25}X is 10%10\%, what is the percentage abundance of the isotope 26X^{26}X?

Answer: 11 %

Answer

The percentage abundance of 26X^{26}X is 11%11\%.
By setting the percentage abundance of 24X^{24}X as xx and 26X^{26}X as zz, given 25X=10%^{25}X = 10\%, we have x+z=90%x + z = 90\%. Using the relative atomic mass formula 24x+25(10)+26z=243224x + 25(10) + 26z = 2432 and substituting x=90zx = 90 - z yields 2410+2z=24322410 + 2z = 2432, solving to z=11%z = 11\%.

Step-by-Step Solution

1
Formulate the abundance relation for the three isotopes.
The sum of abundances is x+10+z=100%x + 10 + z = 100\%, which gives x=90zx = 90 - z.
The sum of percentage abundances of all naturally occurring isotopes of an element must equal 100%.
2
Set up the weighted relative atomic mass equation.
24x+25(10)+26z=243224x + 25(10) + 26z = 2432.
Relative atomic mass is the weighted average of isotopic masses based on fractional abundance.
3
Substitute x=90zx = 90 - z and solve for zz.
24(90z)+250+26z=2432    2410+2z=2432    z=11%24(90 - z) + 250 + 26z = 2432 \implies 2410 + 2z = 2432 \implies z = 11\%.
Substituting xx reduces the equation to a single variable zz, representing the percentage abundance of 26X^{26}X.

Key Concept

Calculation of Isotopic Abundances from Relative Atomic Mass
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